An isolable o-quinodimethane and its fixation of molecular oxygen to give an endoperoxide

被引：23

作者：

Ghereg, Dumitru ^{[1
,2
]}

El Kettani, Sakina Ech-Cherif ^{[3
]}

Lazraq, Mohamed ^{[3
]}

Ranaivonjatovo, Henri ^{[1
,2
]}

Schoeller, Wolfgang W. ^{[4
]}

Escudie, Jean ^{[1
,2
]}

Gornitzka, Heinz ^{[5
,6
]}

机构：

[1] Univ Toulouse, UPS, LHFA, F-31062 Toulouse, France

[2] CNRS, UMR 5069, LHFA, F-31062 Toulouse, France

[3] Univ Sidi Mohamed Ben Abdellah, Fac Sci Dhar El Mehraz, Lab Ingn Mat Organ & Mol, Fes, Morocco

[4] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA

[5] CNRS, Chim Coordinat Lab, F-31077 Toulouse 4, France

[6] Univ Toulouse, UPS, INP, LCC, F-31077 Toulouse, France

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 32期

关键词：

GERMENE MES(2)GE=CR2; ORGANIC-SYNTHESIS; TRIPLET OXYGEN; DOUBLE-BOND; REACTIVITY; DERIVATIVES; HAMIGERANS; SYSTEM; INDOLE; C-60;

D O I：

10.1039/b910001f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Addition of the germene Mes(2)Ge=CR2 to 1,4-naphthoquinone yields a singular o-quinodimethane which gives Diels-Alder reactions at room temperature and reacts cleanly with oxygen to form an endoperoxide.

引用

页码：4821 / 4823

页数：3

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