Palladium-catalyzed intramolecular reductive olefin hydrocarbonation: benzylic hydrogen serving as a new hydrogen donor

被引：18

作者：

Dong, Xu ^{[1
]}

Cui, Jie ^{[1
]}

Song, Jian ^{[1
]}

Han, Ying ^{[1
]}

Liu, Qing ^{[1
]}

Dong, Yunhui ^{[1
]}

Liu, Hui ^{[1
]}

机构：

[1] Shandong Univ Technol, Sch Chem Engn, 266 West Xincun Rd, Zibo 255049, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 36期

基金：

中国国家自然科学基金;

关键词：

BOND-DISSOCIATION ENERGIES; ORGANIC-SYNTHESIS; ALKYL IODIDES; ATOM-TRANSFER; C-O; ALKENES; REAGENTS; HYDROAMINATION; AMIDATION; HALIDES;

D O I：

10.1039/c7cc01423f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A palladium-catalyzed intramolecular hydrocarbonation of unactivated alkenes was achieved, in which toluene is used as a hydrogen donor for the first time. The radical transfer hydrogenation is designed and realized based on the Bond Dissociation Energy (BDE) value. A toluene derivative, which is cheap, readily available and easy to handle, serves as a new hydrogen donor in radical involved reactions, providing a novel and promising perspective for future reductive reactions.

引用

页码：4903 / 4906

页数：4

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