Self-assembling polymeric mixed donor (O/N) N-ethylmorpholine adducts of alane (AlH3)

被引：13

作者：

Andrews, PC

Raston, CL

Skelton, BW

White, AH

机构：

[1] MONASH UNIV,DEPT CHEM,CLAYTON,VIC 3168,AUSTRALIA

[2] UNIV WESTERN AUSTRALIA,DEPT CHEM,NEDLANDS,WA 6907,AUSTRALIA

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 02期

关键词：

D O I：

10.1039/a607916d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The 2:3 and 1:2 stoichiometric reactions of N-ethyl morpholine with the Et(2)O adduct of A1H(3), prepared from LiAlH4 and H2SO4 in E(t)2O at -80 degrees C, afford alane-rich hydride-bridged polymers exhibiting a range of bonding modes of Lewis bases to AlH3 including unprecedented mono Al ... H hydride bridging.

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页码：245 / 246

页数：2

相关论文

共 12 条

[1] MIXED-DONOR AND MONOMERIC N-DONOR ADDUCTS OF ALANE [J].

ATWOOD, JL ;

BUTZ, KW ;

GARDINER, MG ;

JONES, C ;

KOUTSANTONIS, GA ;

RASTON, CL ;

ROBINSON, KD .

INORGANIC CHEMISTRY, 1993, 32 (16) :3482-3487

[2] LASER-INDUCED CHEMICAL VAPOR-DEPOSITION OF ALUMINUM [J].

BAUM, TH ;

LARSON, CE ;

JACKSON, RL .

APPLIED PHYSICS LETTERS, 1989, 55 (12) :1264-1266

[3] ADSORPTION OF GALLANE ON OXIDIZED SILICON [J].

BUTZ, KW ;

ELMS, FM ;

RASTON, CL ;

LAMB, RN ;

PIGRAM, PJ .

INORGANIC CHEMISTRY, 1993, 32 (19) :3985-3986

[4] ALUMINUM THIN-FILM GROWTH BY THE THERMAL-DECOMPOSITION OF TRIETHYLAMINE ALANE [J].

DUBOIS, LH ;

ZEGARSKI, BR ;

GROSS, ME ;

NUZZO, RG .

SURFACE SCIENCE, 1991, 244 (1-2) :89-95

[5] ADSORPTION OF THE TRIMETHYLAMINE ADDUCT OF ALUMINUM-HYDRIDE ON SILICON-OXIDE [J].

ELMS, FM ;

LAMB, RN ;

PIGRAM, PJ ;

GARDINER, MG ;

WOOD, BJ ;

RASTON, CL .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (19) :1423-1425

[6] Trimethylamine Complexes of Alane as Precursors for the Low-Pressure Chemical Vapor Deposition of Aluminum [J].

Gladfelter, Wayne L. ;

Boyd, David C. ;

Jensen, Klays F. .

CHEMISTRY OF MATERIALS, 1989, 1 (03) :339-343

[7] PREPARATION AND CRYSTAL-STRUCTURES OF ALUMINUM-HYDRIDE ADDUCTS WITH TETRAHYDROFURAN [ALH3.OC4H8]2 AND ALH3.2OC4H8 [J].

GORRELL, IB ;

HITCHCOCK, PB ;

SMITH, JD .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (02) :189-190

[8] LEWIS BASE ADDUCTS OF ALANE AND GALLANE [J].

JONES, C ;

KOUTSANTONIS, GA ;

RASTON, CL .

POLYHEDRON, 1993, 12 (15) :1829-1848

[9]

MELAS AA, 1988, Patent No. 4740606

[10] RECENT DEVELOPMENTS IN THE CHEMISTRY OF ALANE (ALH3) AND GALLANE (GAH3) [J].

RASTON, CL .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 475 (1-2) :15-24