Mebendazole: New and efficient corrosion inhibitor for mild steel in acid medium

被引：228

作者：

Ahamad, Ishtiaque ^{[1
]}

Quraishi, M. A. ^{[1
]}

机构：

[1] Banaras Hindu Univ, Inst Technol, Dept Appl Chem, Varanasi 221005, Uttar Pradesh, India

来源：

CORROSION SCIENCE | 2010年 / 52卷 / 02期

关键词：

Mild steel; Acid solutions; Polarization; Weight loss; Adsorption; IMPEDANCE SPECTROSCOPY; TRIAZOLE DERIVATIVES; ADSORPTION; BEHAVIOR; DRUGS; INTERFACE; THIOUREA; SURFACE; COPPER;

D O I：

10.1016/j.corsci.2009.10.012

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The inhibition performance of mebendazole, a drug, on mild steel in molar hydrochloric acid solution was studied by weight loss and electrochemical methods. The maximum inhibition efficiency 96.2% was observed in presence of 2.54 x 10(-4) M inhibitor. Polarization measurements showed that the inhibitor is mixed type. Data obtained from EIS studies were analyzed to model inhibition process through appropriate equivalent circuit models. The results obtained from the different methods are in good agreement. The various thermodynamic parameters of dissolution and adsorption processes were evaluated in order to elaborate adsorption mechanism. Adsorption of inhibitor obeyed Langmuir adsorption isotherm model. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：651 / 656

页数：6

共 55 条

[31] IMPEDANCE SPECTROSCOPY AND ITS USE IN ANALYZING THE STEADY-STATE AC RESPONSE OF SOLID AND LIQUID ELECTROLYTES [J].

MACDONALD, JR .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1987, 223 (1-2) :25-50

[32] RECORDING AND ANALYSIS OF AC IMPEDANCE DATA FOR CORROSION STUDIES .1. BACKGROUND AND METHODS OF ANALYSIS [J].

MANSFELD, F .

CORROSION, 1981, 37 (05) :301-307

[33] Inhibiting effects of 3,5-bis(n-pyridyl)-4-amino-1,2,4-triazoles on the corrosion for mild steel in 1M HCl medium [J].

Mernari, B ;

El Attari, H ;

Traisnel, M ;

Bentiss, F ;

Lagrenee, M .

CORROSION SCIENCE, 1998, 40 (2-3) :391-399

[34] Short-term deterioration of polymer-coated 55% Al-Zn .1. Behavior of thin polymer films [J].

Mertens, SF ;

Xhoffer, C ;

DeCooman, BC ;

Temmerman, E .

CORROSION, 1997, 53 (05) :381-388

[35] Inhibition of iron corrosion in acid solutions by Cefatrexyl: Behaviour near and at the corrosion potential [J].

Morad, M. S. .

CORROSION SCIENCE, 2008, 50 (02) :436-448

[36] THE EFFECT OF MOLECULAR-STRUCTURE ON HYDROGEN PERMEATION AND THE CORROSION INHIBITION OF MILD-STEEL IN ACIDIC SOLUTIONS [J].

MURALIDHARAN, S ;

QURAISHI, MA ;

IYER, SVK .

CORROSION SCIENCE, 1995, 37 (11) :1739-1750

[37] Antifungal drugs as corrosion inhibitors for aluminium in 0.1 M HCl [J].

Obot, I. B. ;

Obi-Egbedi, N. O. ;

Umoren, S. A. .

CORROSION SCIENCE, 2009, 51 (08) :1868-1875

[38] A STUDY OF PYRITE SOLUTION INTERFACE BY IMPEDANCE SPECTROSCOPY [J].

PANG, J ;

BRICENO, A ;

CHANDER, S .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1990, 137 (11) :3447-3455

[39] AC and DC study of the temperature effect on mild steel corrosion in acid media in the presence of benzimidazole derivatives [J].

Popova, A ;

Sokolova, E ;

Raicheva, S ;

Christov, M .

CORROSION SCIENCE, 2003, 45 (01) :33-58

[40] Influence of tramadol [2-[(dimethylamino)methyl]-1-(3-methoxyphenyl) cyclohexanol hydrate] on corrosion inhibition of mild steel in acidic media [J].

Prabhu, R. A. ;

Shanbhag, A. V. ;

Venkatesha, T. V. .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 2007, 37 (04) :491-497

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