Mebendazole: New and efficient corrosion inhibitor for mild steel in acid medium

被引：223
作者：
Ahamad, Ishtiaque [1 ]
Quraishi, M. A. [1 ]
机构：
[1] Banaras Hindu Univ, Inst Technol, Dept Appl Chem, Varanasi 221005, Uttar Pradesh, India
来源：
CORROSION SCIENCE | 2010年 / 52卷 / 02期
关键词：
Mild steel; Acid solutions; Polarization; Weight loss; Adsorption; IMPEDANCE SPECTROSCOPY; TRIAZOLE DERIVATIVES; ADSORPTION; BEHAVIOR; DRUGS; INTERFACE; THIOUREA; SURFACE; COPPER;
D O I：
10.1016/j.corsci.2009.10.012
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The inhibition performance of mebendazole, a drug, on mild steel in molar hydrochloric acid solution was studied by weight loss and electrochemical methods. The maximum inhibition efficiency 96.2% was observed in presence of 2.54 x 10(-4) M inhibitor. Polarization measurements showed that the inhibitor is mixed type. Data obtained from EIS studies were analyzed to model inhibition process through appropriate equivalent circuit models. The results obtained from the different methods are in good agreement. The various thermodynamic parameters of dissolution and adsorption processes were evaluated in order to elaborate adsorption mechanism. Adsorption of inhibitor obeyed Langmuir adsorption isotherm model. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码：651 / 656
页数：6
相关论文
共 55 条
  • [21] APPLICATION OF THE AC ADMITTANCE TECHNIQUE TO DOUBLE-LAYER STUDIES ON POLYCRYSTALLINE GOLD ELECTRODES
    FAWCETT, WR
    KOVACOVA, Z
    MOTHEO, AJ
    FOSS, CA
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1992, 326 (1-2): : 91 - 103
  • [22] Evaluation of the inhibitor effect of L-ascorbic acid on the corrosion of mild steel
    Ferreira, ES
    Giacomelli, C
    Giacomelli, FC
    Spinelli, A
    [J]. MATERIALS CHEMISTRY AND PHYSICS, 2004, 83 (01) : 129 - 134
  • [23] Impedance study of reinforcing steel in simulated pore solution with tannin
    Flis, J
    Zakroczymski, T
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (08) : 2458 - 2464
  • [24] Inhibition of mild steel corrosion in hydrochloric acid solution by triazole derivatives - Part I. Polarization and EIS studies
    Hassan, Hamdy H.
    Abdelghani, Essam
    Amin, Mohammed A.
    [J]. ELECTROCHIMICA ACTA, 2007, 52 (22) : 6359 - 6366
  • [25] The inhibition of mild steel corrosion in acidic medium by 1-methyl-3-pyridin-2-yl-thiourea
    Hosseini, S. M. A.
    Azimi, A.
    [J]. CORROSION SCIENCE, 2009, 51 (04) : 728 - 732
  • [26] Technical note:: Concerning the conversion of the constant phase element parameter Y0 into a capacitance
    Hsu, CH
    Mansfeld, F
    [J]. CORROSION, 2001, 57 (09) : 747 - 748
  • [27] ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY (EIS) OF CORROSION PROCESSES ON INHOMOGENEOUS SURFACES
    JUTTNER, K
    [J]. ELECTROCHIMICA ACTA, 1990, 35 (10) : 1501 - 1508
  • [28] ACID CORROSION INHIBITION OF NICKEL BY 2-(TRIPHENOSPHORANYLIDENE) SUCCINIC ANHYDRIDE
    KHAMIS, E
    BELLUCCI, F
    LATANISION, RM
    ELASHRY, ESH
    [J]. CORROSION, 1991, 47 (09) : 677 - 686
  • [29] Study of the mechanism and inhibiting efficiency of 3,5-bis(4-methylthiophenyl)-4H-1,2,4-triazole on mild steel corrosion in acidic media
    Lagrenée, M
    Mernari, B
    Bouanis, M
    Traisnel, M
    Bentiss, F
    [J]. CORROSION SCIENCE, 2002, 44 (03) : 573 - 588
  • [30] Some new triazole derivatives as inhibitors for mild steel corrosion in acidic medium
    Li, Wei-hua
    He, Qiao
    Zhang, Sheng-tao
    Pei, Chang-ling
    Hou, Bao-rong
    [J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 2008, 38 (03) : 289 - 295
123456