Mebendazole: New and efficient corrosion inhibitor for mild steel in acid medium

被引:228
作者
Ahamad, Ishtiaque [1 ]
Quraishi, M. A. [1 ]
机构
[1] Banaras Hindu Univ, Inst Technol, Dept Appl Chem, Varanasi 221005, Uttar Pradesh, India
关键词
Mild steel; Acid solutions; Polarization; Weight loss; Adsorption; IMPEDANCE SPECTROSCOPY; TRIAZOLE DERIVATIVES; ADSORPTION; BEHAVIOR; DRUGS; INTERFACE; THIOUREA; SURFACE; COPPER;
D O I
10.1016/j.corsci.2009.10.012
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The inhibition performance of mebendazole, a drug, on mild steel in molar hydrochloric acid solution was studied by weight loss and electrochemical methods. The maximum inhibition efficiency 96.2% was observed in presence of 2.54 x 10(-4) M inhibitor. Polarization measurements showed that the inhibitor is mixed type. Data obtained from EIS studies were analyzed to model inhibition process through appropriate equivalent circuit models. The results obtained from the different methods are in good agreement. The various thermodynamic parameters of dissolution and adsorption processes were evaluated in order to elaborate adsorption mechanism. Adsorption of inhibitor obeyed Langmuir adsorption isotherm model. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码:651 / 656
页数:6
相关论文
共 55 条
[1]   Electrochemical studies on the effect of (2E)-3-amino-2-phenylazo-but-2-enenitrile and its derivative on the behaviour of copper in nitric acid [J].
Abd El-Maksoud, S. A. ;
Hassan, H. H. .
MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION, 2007, 58 (05) :369-375
[2]  
Abd El-Rehim SSA, 1999, J APPL ELECTROCHEM, V29, P593
[3]   Rhodanine azosulpha drugs as corrosion inhibitors for corrosion of 304 stainless steel in hydrochloric acid solution [J].
Abdallah, M .
CORROSION SCIENCE, 2002, 44 (04) :717-728
[4]   Antibacterial drugs as corrosion inhibitors for corrosion of aluminium in hydrochloric solution [J].
Abdallah, M .
CORROSION SCIENCE, 2004, 46 (08) :1981-1996
[5]   Inhibiting effects of some quinolines and organic phosphonium compounds on corrosion of mild steel in 3M HCl solution and their adsorption characteristics [J].
Abdel-Aal, MS ;
Morad, MS .
BRITISH CORROSION JOURNAL, 2001, 36 (04) :253-260
[6]   Inhibitive action of some plant extracts on the corrosion of steel in acidic media [J].
Abdel-Gaber, A. M. ;
Abd-El-Nabey, B. A. ;
Sidahmed, I. M. ;
El-Zayady, A. M. ;
Saadawy, M. .
CORROSION SCIENCE, 2006, 48 (09) :2765-2779
[7]   Bis (benzimidazol-2-yl) disulphide: An efficient water soluble inhibitor for corrosion of mild steel in acid media [J].
Ahamad, Ishtiaque ;
Quraishi, M. A. .
CORROSION SCIENCE, 2009, 51 (09) :2006-2013
[8]  
[Anonymous], 1987, CORROSION MECH
[9]  
[Anonymous], 1973, Corrosion Inhibition
[10]   THE EFFECT OF THIOUREA ON THE CORROSION KINETICS OF MILD-STEEL IN H2SO4 [J].
ATEYA, BG ;
ELANADOULI, BE ;
ELNIZAMY, FM .
CORROSION SCIENCE, 1984, 24 (06) :497-507