Synthesis and crystal structures of two zinc(II) complexes derived from 4-bromo-2-(cyclopentyliminomethyl)phenol with different solvents

被引：2

作者：

Hong, Z. ^{[1
]}

机构：

[1] Liaodong Univ, Coll Chem Engn & Mat Sci, Dandong 118003, Peoples R China

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2009年 / 35卷 / 11期

关键词：

SCHIFF-BASE; SILVER(I) COMPLEXES; SOLID-STATE; NICKEL(II); ANTIBACTERIAL; COPPER(II); COBALT(II); LIGAND; ACID;

D O I：

10.1134/S1070328409110074

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new mononuclear zinc(II) complexes, [ZnL(2)] (I) and [ZnL(2)] center dot 2MeOH (II) (HL = 4-bromo-2-(cyclopentyliminomethyl)phenol), were synthesized by the reaction of the Schiff base HL with zinc acetate in ethanol and methanol solutions, respectively. Both complexes were characterized by elemental analyses and single-crystal X-ray diffraction. The crystal of I is orthorhombic: space group Pbca, a = 14.711(3), b = 13.223(3), c = 24.870(5) , V = 4837.8(18) (3), Z = 8. The crystal of II is monoclinic: space group C2/c, a = 20.581(5), b = 10.660(3), c = 15.428(4) , beta = 119.919(3)A degrees, V = 2933.7(13) (3), Z = 4. The Zn atom in each complex is four-coordinated by two imine N and two phenolic O atoms, forming a tetrahedral geometry. Complex II possesses crystallographic two-fold rotation axis symmetry.

引用

页码：830 / 834

页数：5

共 12 条

[1] Bis-salicylaldiminato complexes of zinc.: Examination of the catalyzed Epoxide/CO2 copolymerization [J].

Darensbourg, DJ ;

Rainey, P ;

Yarbrough, J .

INORGANIC CHEMISTRY, 2001, 40 (05) :986-993

[2] Characterization and crystal structure of some Schiff base copper(II) complexes derived from enantiomeric pairs of chiral amines [J].

Fernandez-G, Juan M. ;

Ausbun-Valdes, Cecilia ;

Gonzalez-Guerrero, Erika E. ;

Toscano, Ruben A. .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2007, 633 (08) :1251-1256

[3] Unusual manifestation of closed-shell interactions in silver(I) complexes:: Crystal structure of catena-bis(4-aminobenzoato)disilver(I) acetone solvate with ligand unsupported chains of repeated rhombohedral Ag4 units [J].

Kristiansson, O .

INORGANIC CHEMISTRY, 2001, 40 (20) :5058-+

[4] Synthesis and characterization of water-soluble silver(I) complexes with L-histidine (H2his) and (S)-(-)-2-pyrrolidone-5-carboxylic acid (H2pyrrld) showing a wide spectrum of effective antibacterial and antifungal activities.: Crystal structures of chiral helical polymers [Ag(Hhis)]n and {[Ag(Hpyrrld)]2}n in the solid state [J].

Nomiya, K ;

Takahashi, S ;

Noguchi, R ;

Nemoto, S ;

Takayama, T ;

Oda, M .

INORGANIC CHEMISTRY, 2000, 39 (15) :3301-3311

[5] Designing, Structural Elucidation, Comparison of DNA Cleavage, and Antibacterial Activity of Metal(II) Complexes Containing Tetradentate Schiff Base [J].

Raman, N. ;

Raja, S. J. ;

Joseph, J. ;

Sakthivel, A. .

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2008, 34 (11) :842-848

[6] Directed synthesis of a heterobimetallic complex based on a novel unsymmetric double-Schiff-base ligand: Preparation, characterization, reactivity and structures of hetero- and homobimetallic nickel(II) and zinc(II) complexes [J].

Roth, Arne ;

Buchhoz, Axel ;

Rudolph, Manfred ;

Schuetze, Eileen ;

Kothe, Erika ;

Plass, Winfried .

CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (05) :1571-1583

[7]

Sakiyama H., 1990, DALTON T, P2935

[8]

SHELFO SW, 1997, ATLAS UROL CLIN N AM, V5, P1

[9] Nickel(II) and cobalt(II) complexes with products of condensation of 1-aminonaphthalene, 2-aminonaphthalenesulfonic-5 acid, and aromatic carbinols [J].

Skorokhod, LS ;

Seifullina, II ;

Dzhambek, SA .

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2002, 28 (09) :643-646

[10] The interconversion of dichlorobis(N-n-propylsalicylaldimine)zinc(II) and bis(N-n-propylsalicylaldiminato)zinc(II) [J].

Torzilli, MA ;

Colquhoun, S ;

Doucet, D ;

Beer, RH .

POLYHEDRON, 2002, 21 (07) :697-704

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