Palladium-mediated synthesis of a new eight-membered heterocycle

被引：0
作者：
Bocelli, G
Catellani, M [1 ]
Cugini, F
Ferraccioli, R
机构：
[1] CNR, Ctr Studio Strutturist Diffrattometr, Parco Area Sci 17-A, I-43100 Parma, Italy
[2] Dipartimento Chim Organ & Ind, I-43100 Parma, Italy
[3] CNR, Ctr Sintesi & Stereochim Speciali Sistemi Organ, I-20133 Milan, Italy
来源：
ARKIVOC | 2002年
关键词：
palladium catalysis; eight-membered heterocycle; o-iodoacetanilide; carbon monoxide;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The eight-membered heterocycle 3 has been prepared in 94% isolated yield starting from phenylnorbornylpalladium chloride dimer, o-iodoacetanilide and carbon monoxide in DMF at room temperature. Compound 3 has been unequivocally characterized by X-ray single crystal diffraction. Formation of 3 must involve coordination of the amido group to palladium which prevents ring closure to a hexahydromethanotriphenylene derivative.
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页码：120 / 126
页数：7
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