Recent advances on tailor-made titanium catalysts for biopolymer synthesis

被引：56
作者：
Le Roux, Erwan [1 ]
机构：
[1] Univ Bergen, Dept Chem, N-5007 Bergen, Norway
来源：
COORDINATION CHEMISTRY REVIEWS | 2016年 / 306卷
关键词：
Titanium; Bio-derived monomer; CO2; Polyester; Polycarbonate; Poly(methyl metacrylate); RING-OPENING POLYMERIZATION; GROUP-4; METAL-COMPLEXES; X-RAY STRUCTURES; LIGANDS EFFICIENT CATALYSTS; EPSILON-CAPROLACTONE; STRUCTURAL-CHARACTERIZATION; CYCLIC ESTERS; L-LACTIDE; OLEFIN POLYMERIZATION; METALLOCENE COMPLEXES;
D O I：
10.1016/j.ccr.2015.06.006
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
After years of influence of titanium-based Ziegler-Natta catalysts on "petropolymers" synthesis, titanium complexes are experiencing a resurgence in research efforts as sustainable catalysts for biopolymer synthesis. This review article summarizes the different classes of well-defined homogeneous and heterogeneous titanium catalysts supported by various multidentate ancillary ligands for the synthesis of polyesters, polycarbonates and poly(methyl metacrylate) derivatives which are biodegradable and/or synthesized from renewable monomers. Special attention is given to the relationships between the electronic and steric effects of catalysts governing the activity, control and stereoselectivity whenever applicable. (C) 2015 Elsevier B.V. All rights reserved.
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页码：65 / 85
页数：21
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