Self-assembly of a water chain with tetrameric and decameric clusters in the channel of a mixed-valence CuICuII complex

被引：59

作者：

Hu, Ning-Hai ^{[1
]}

Li, Zhi-Gang ^{[1
]}

Xu, Jing-Wei ^{[1
]}

Jia, Heng-Qing ^{[1
]}

Niu, Jia-Jia ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, Changchun 130022, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2007年 / 7卷 / 01期

关键词：

(H2O)(N); HEXAMER; ICE; SPECTROSCOPY; MOLECULES; PENTAMER; SPECTRA; POLYMER; LAYER; TAPES;

D O I：

10.1021/cg060641r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of Cu(BF4)(2) with pyridine-2,6-dicarboxylic acid (H(2)pydc) and trans-1,2-bis(4-pyridyl)ethylene (bpe) under hydrothermal conditions afforded a porous mixed-valence (CuCuII)-Cu-I coordination polymer. Coexistence of tetrameric and decameric water clusters within the channels of the complex leads to a novel water chain. The metal-organic framework provides both hydrophilic and hydrophobic environments for stabilizing the clusters and retains its integrity upon dehydration and rehydration.

引用

页码：15 / 17

页数：3

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