A Highly Energetic N-Rich Metal-Organic Framework as a New High-Energy-Density Material

被引：62
作者：
Zhang, Huabin [1 ,2 ]
Zhang, Mingjian [1 ]
Lin, Ping [1 ]
Malgras, Victor [2 ]
Tang, Jing [2 ,3 ]
Alshehri, Saad M. [4 ]
Yamauchi, Yusuke [1 ,3 ,4 ]
Du, Shaowu [1 ]
Zhang, Jian [1 ]
机构：
[1] Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China
[2] Natl Inst Mat Sci, World Premier Int WPI Res Ctr Mat Nanoarchitecton, 1-1 Namiki, Tsukuba, Ibaraki 3050044, Japan
[3] Waseda Univ, Fac Sci & Engn, Shinjuku Ku, 3-4-1 Okubo, Tokyo 1690072, Japan
[4] King Saud Univ, Coll Sci, Dept Chem, Riyadh 11451, Saudi Arabia
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2016年 / 22卷 / 03期
基金：
中国国家自然科学基金;
关键词：
helical structures; high-energy materials; hydrothermal synthesis; metal-organic frameworks; N ligands; SELECTIVE SEPARATION; CRYSTAL-STRUCTURES; CENTER-DOT; DETONATION; THERMOSTABILITY; INSENSITIVITY; POLYMERS; STRATEGY; CHANNELS; SITES;
D O I：
10.1002/chem.201503561
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Metal-organic framework (MOF)-based energetic material [Cu-3(MA)(2)(N-3)(3)] (1; MA=melamine) was synthesized and structurally characterized (47.55% N). The structural analysis revealed the existence of unusual multiwalled tubular channels and interweaving of single and double helical units in 1. The standard molar enthalpy of formation was found to be 1788.73 kJmol(-1), which is the highest value among previously reported MOF-based energetic materials. The calculated detonation properties showed that 1 can be used as a potential explosive. Sensitivity tests revealed that 1 is insensitive and thus can function as a high-energy-density material with a favorable level of safety.
引用
收藏
页码：1141 / 1145
页数：5
相关论文
共 43 条
  • [31] 2-6
  • [32] Design and generation of extended zeolitic metal-organic frameworks (ZMOFs): Synthesis and crystal structures of zinc(II) imidazolate polymers with zeolitic topologies
    Tian, Yun-Qi
    Zhao, Yu-Ming
    Chen, Zhen-Xia
    Zhang, Guang-Ning
    Weng, Lin-Hong
    Zhao, Dong-Yuan
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (15) : 4146 - 4154
  • [33] Facile synthesis of nanoporous carbons with controlled particle sizes by direct carbonization of monodispersed ZIF-8 crystals
    Torad, Nagy L.
    Hu, Ming
    Kamachi, Yuichiro
    Takai, Kimiko
    Imura, Masataka
    Naito, Masanobu
    Yamauchi, Yusuke
    [J]. CHEMICAL COMMUNICATIONS, 2013, 49 (25) : 2521 - 2523
  • [34] Homochiral Zinc(II) Coordination Compounds Based on In-Situ-Generated Chiral Amino Acid-Tetrazole Ligands: Circular Dichroism, Excitation Light-Induced Tunable Photoluminescence, and Energetic Performance
    Wang, Shuai-Hua
    Zheng, Fa-Kun
    Zhang, Ming-Jian
    Liu, Zhi-Fa
    Chen, Jun
    Xiao, Yu
    Wu, A-Qing
    Guo, Guo-Cong
    Huang, Jin-Shun
    [J]. INORGANIC CHEMISTRY, 2013, 52 (17) : 10096 - 10104
  • [35] Unprecedented interweaving of single-helical and unequal double-helical chains into chiral metal-organic open frameworks with multiwalled tubular structures
    Wang, Su-Na
    Xing, Hang
    Li, Yi-Zhi
    Bai, Junfeng
    Scheer, Manfred
    Pan, Yi
    You, Xiao-Zeng
    [J]. CHEMICAL COMMUNICATIONS, 2007, (22) : 2293 - 2295
  • [36] A Simple Method for the Prediction of the Detonation Performances of Metal-Containing Explosives
    Wang, Yuan
    Zhang, Jichuan
    Su, Hui
    Li, Shenghua
    Zhang, Shaowen
    Pang, Siping
    [J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2014, 118 (25) : 4575 - 4581
  • [37] Preparation, Crystal Structure, Thermal Decomposition, and Explosive Properties of a Novel Energetic Compound [Zn(N2H4)2(N3)2]n: A New High-Nitrogen Material (N=65.60%)
    Wu, Bi-Dong
    Yang, Li
    Wang, Shi-Wei
    Zhang, Tong-Lai
    Zhang, Jian-Guo
    Zhou, Zun-Ning
    Yu, Kai-Bei
    [J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2011, 637 (3-4): : 450 - 455
  • [38] High CO2 and H2 Uptake in an Anionic Porous Framework with Amino-Decorated Polyhedral Cages
    Zhai, Quan-Guo
    Lin, Qipu
    Wu, Tao
    Wang, Le
    Zheng, Shou-Tian
    Bu, Xianhui
    Feng, Pingyun
    [J]. CHEMISTRY OF MATERIALS, 2012, 24 (14) : 2624 - 2626
  • [39] Encapsulation of an Interpenetrated Diamondoid Inorganic Building Block in a Metal-Organic Framework
    Zhang, Huabin
    Lin, Ping
    Chen, Erxia
    Tan, Yanxi
    Wen, Tian
    Aldalbahi, Ali
    Alshehri, Saad M.
    Yamauchi, Yusuke
    Du, Shaowu
    Zhang, Jian
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (13) : 4931 - 4934
  • [40] New coordination motifs of melamine directed by N-H•••X (X = cl or br) hydrogen bonds
    Zhang, Lei
    Zhang, Jian
    Li, Zhao-Ji
    Cheng, Jian-Kai
    Yin, Pei-Xiu
    Yao, Yuan-Gen
    [J]. INORGANIC CHEMISTRY, 2007, 46 (15) : 5838 - 5840
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