Redox conversions in crystalline compounds based on macrocyclic complexes of nickel(II)/(III) and aromatic carboxylates

被引：4

作者：

Andriichuk, I. L. ^{[1
]}

Tsymbal, L. V. ^{[1
]}

Lampeka, Ya. D. ^{[1
]}

机构：

[1] Natl Acad Sci Ukraine, LV Pisarzhevskii Inst Phys Chem, UA-03028 Kiev, Ukraine

来源：

THEORETICAL AND EXPERIMENTAL CHEMISTRY | 2009年 / 45卷 / 04期

关键词：

macrocyclic complexes; nickel(II); nickel(III); carboxylates; metal-organic skeletons; coordination polymers; COPPER(II) COMPLEXES; COORDINATION; FRAMEWORKS;

D O I：

10.1007/s11237-009-9090-9

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

It is shown that conversion of nickel(II) complexes, in the composition of crystalline compounds of various structures, into nickel(III) leads to the preparation of new redox-active metal-organic skeletons. The structure of the chromophore of the metal ion and the chemical properties of the compounds formed by this process (thermal stability, reactivity) depend to an important extent on the nature of the construction blocks which makes possible the creation of new materials with controlled properties.

引用

页码：252 / 257

页数：6

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