Novel Bis[N-alkyl-N-(2-diphenylphosphinylethyl)]diglycolamides: Synthesis and NMR Spectroscopy Studies

被引：3

作者：

Bondarenko, N. A. ^{[1
,2
]}

Tcarkova, K. V. ^{[1
,2
]}

Belus, S. K. ^{[2
]}

Artyushin, O. I. ^{[3
]}

Peregudov, A. S. ^{[3
]}

机构：

[1] Natl Res Ctr Kurchatov Inst, Inst Chem Reagents & High Purity Chem Subst, Moscow 107076, Russia

[2] Natl Res Ctr Kurchatov Inst, Moscow 123182, Russia

[3] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2021年 / 91卷 / 02期

关键词：

diglycolamides; amidation; O-trimethylsilyldiphenylphosphinite; diphenyl(2-phenoxyethyl)phosphine oxide; N-alkyl-N-(2-diphenylphosphinylethyl)amines; pentadentate bis[N-alkyl-N-(2-diphenylphosphinylethyl)]diglycolamides; NMR spectroscopy;

D O I：

10.1134/S1070363221020055

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pentadentate bis[N-alkyl-N-(2-diphenylphosphinylethyl)]diglycolamides [Ph2P(O)CH2CH2N(R)center dot C(O)CH2](2)O, where R Me, Bu, Oct, were synthesized by reaction of diglycolyl chloride with N-alkyl-N-(2-diphenylphosphinylethyl)amines Ph2P(O)CH2CH2NHR obtained by reacting diphenyl(2-phenoxyethyl)phosphine oxide with primary alkylamines in DMSO in the presence of an aqueous alkali. Structure of the prepared compounds was studied by H-1, C-13, and P-31 NMR spectroscopy.

引用

页码：181 / 189

页数：9

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