Novel Bis[N-alkyl-N-(2-diphenylphosphinylethyl)]diglycolamides: Synthesis and NMR Spectroscopy Studies

被引：3

作者：

Bondarenko, N. A. ^{[1
,2
]}

Tcarkova, K. V. ^{[1
,2
]}

Belus, S. K. ^{[2
]}

Artyushin, O. I. ^{[3
]}

Peregudov, A. S. ^{[3
]}

机构：

[1] Natl Res Ctr Kurchatov Inst, Inst Chem Reagents & High Purity Chem Subst, Moscow 107076, Russia

[2] Natl Res Ctr Kurchatov Inst, Moscow 123182, Russia

[3] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2021年 / 91卷 / 02期

关键词：

diglycolamides; amidation; O-trimethylsilyldiphenylphosphinite; diphenyl(2-phenoxyethyl)phosphine oxide; N-alkyl-N-(2-diphenylphosphinylethyl)amines; pentadentate bis[N-alkyl-N-(2-diphenylphosphinylethyl)]diglycolamides; NMR spectroscopy;

D O I：

10.1134/S1070363221020055

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pentadentate bis[N-alkyl-N-(2-diphenylphosphinylethyl)]diglycolamides [Ph2P(O)CH2CH2N(R)center dot C(O)CH2](2)O, where R Me, Bu, Oct, were synthesized by reaction of diglycolyl chloride with N-alkyl-N-(2-diphenylphosphinylethyl)amines Ph2P(O)CH2CH2NHR obtained by reacting diphenyl(2-phenoxyethyl)phosphine oxide with primary alkylamines in DMSO in the presence of an aqueous alkali. Structure of the prepared compounds was studied by H-1, C-13, and P-31 NMR spectroscopy.

引用

页码：181 / 189

页数：9

共 27 条

[1] Chemistry of Diglycolamides: Promising Extractants for Actinide Partitioning [J].

Ansari, Seraj A. ;

Pathak, Priyanath ;

Mohapatra, Prasanta K. ;

Manchanda, Vijay K. .

CHEMICAL REVIEWS, 2012, 112 (03) :1751-1772

[2] New Tridentate Carbamoylmethylphosphine Oxides: Synthesis and NMR Spectra [J].

Bondarenko, N. A. ;

Belus', S. K. ;

Artyushin, O. I. ;

Peregudov, A. S. .

RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2020, 90 (12) :2273-2280

[3] Synthesis of nonsymmetrical dialkylamines on the basis of diphenylphosphinic amides [J].

Bondarenko, N. A. ;

Kharlamov, A. V. ;

Vendilo, A. G. .

RUSSIAN CHEMICAL BULLETIN, 2009, 58 (09) :1872-1885

[4]

Bondarenko N.A., 2018, P SCI C DED 115 ANN, P72

[5]

BONDARENKO NA, 1989, ZH OBSHCH KHIM+, V59, P1533

[6]

Bondarenko NA, 1999, RUSS J GEN CHEM, V69, P1016

[7] BETA-HYDROXY ETHYLDIPHENYLPHOSPHINE AND BETA-ETHOXYETHYLDIPHENYLPHOSPHINE OXIDES AS EQUIVALENTS OF VINYLDIPHENYLPHOSPHINE OXIDE IN ADDITION-REACTIONS [J].

BONDARENKO, NA ;

RUDOMINO, MV ;

TSVETKOV, EN .

BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1990, 39 (09) :1989-1989

[8] PHOSPHORUS-CONTAINING PODANDS .10. AN IMPROVED METHOD FOR SYNTHESIZING OLIGO(ETHYLENE GLYCOL) BIS[2-(DIPHENYLPHOSPHINOYL)ETHYL] ETHERS AND THEIR COMPLEX-FORMING PROPERTIES WITH RESPECT TO ALKALI-METAL-CATIONS IN ANHYDROUS ACETONITRILE [J].

EVREINOV, VI ;

BAULIN, VE ;

VOSTROKNUTOVA, ZN ;

TSVETKOV, EN .

RUSSIAN CHEMICAL BULLETIN, 1993, 42 (03) :472-477

[9]

F��lde��k S., 1963, ACTA PHYS CHEM SZEGE, V9, P134

[10]

Gordon A. J., 1972, CHEMISTS COMPANION H

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