Novel Bis[N-alkyl-N-(2-diphenylphosphinylethyl)]diglycolamides: Synthesis and NMR Spectroscopy Studies

被引：3

作者：

Bondarenko, N. A. ^{[1
,2
]}

Tcarkova, K. V. ^{[1
,2
]}

Belus, S. K. ^{[2
]}

Artyushin, O. I. ^{[3
]}

Peregudov, A. S. ^{[3
]}

机构：

[1] Natl Res Ctr Kurchatov Inst, Inst Chem Reagents & High Purity Chem Subst, Moscow 107076, Russia

[2] Natl Res Ctr Kurchatov Inst, Moscow 123182, Russia

[3] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2021年 / 91卷 / 02期

关键词：

diglycolamides; amidation; O-trimethylsilyldiphenylphosphinite; diphenyl(2-phenoxyethyl)phosphine oxide; N-alkyl-N-(2-diphenylphosphinylethyl)amines; pentadentate bis[N-alkyl-N-(2-diphenylphosphinylethyl)]diglycolamides; NMR spectroscopy;

D O I：

10.1134/S1070363221020055

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pentadentate bis[N-alkyl-N-(2-diphenylphosphinylethyl)]diglycolamides [Ph2P(O)CH2CH2N(R)center dot C(O)CH2](2)O, where R Me, Bu, Oct, were synthesized by reaction of diglycolyl chloride with N-alkyl-N-(2-diphenylphosphinylethyl)amines Ph2P(O)CH2CH2NHR obtained by reacting diphenyl(2-phenoxyethyl)phosphine oxide with primary alkylamines in DMSO in the presence of an aqueous alkali. Structure of the prepared compounds was studied by H-1, C-13, and P-31 NMR spectroscopy.

引用

页码：181 / 189

页数：9

共 27 条

[1] [Anonymous], 1972, CHEMISTS COMPANION H
[2] Chemistry of Diglycolamides: Promising Extractants for Actinide Partitioning
Ansari, Seraj A.
Pathak, Priyanath
Mohapatra, Prasanta K.
Manchanda, Vijay K.
[J]. CHEMICAL REVIEWS, 2012, 112 (03) : 1751 - 1772
[3] New Tridentate Carbamoylmethylphosphine Oxides: Synthesis and NMR Spectra
Bondarenko, N. A.
Belus', S. K.
Artyushin, O. I.
Peregudov, A. S.
[J]. RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2020, 90 (12) : 2273 - 2280
[4] Synthesis of nonsymmetrical dialkylamines on the basis of diphenylphosphinic amides
Bondarenko, N. A.
Kharlamov, A. V.
Vendilo, A. G.
[J]. RUSSIAN CHEMICAL BULLETIN, 2009, 58 (09) : 1872 - 1885
[5] Bondarenko N.A., 2018, P SCI C DED 115 ANN, P72
[6] BONDARENKO NA, 1989, ZH OBSHCH KHIM+, V59, P1533
[7] Bondarenko NA, 1999, RUSS J GEN CHEM, V69, P1016
[8] BETA-HYDROXY ETHYLDIPHENYLPHOSPHINE AND BETA-ETHOXYETHYLDIPHENYLPHOSPHINE OXIDES AS EQUIVALENTS OF VINYLDIPHENYLPHOSPHINE OXIDE IN ADDITION-REACTIONS
BONDARENKO, NA
RUDOMINO, MV
TSVETKOV, EN
[J]. BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1990, 39 (09): : 1989 - 1989
[9] PHOSPHORUS-CONTAINING PODANDS .10. AN IMPROVED METHOD FOR SYNTHESIZING OLIGO(ETHYLENE GLYCOL) BIS[2-(DIPHENYLPHOSPHINOYL)ETHYL] ETHERS AND THEIR COMPLEX-FORMING PROPERTIES WITH RESPECT TO ALKALI-METAL-CATIONS IN ANHYDROUS ACETONITRILE
EVREINOV, VI
BAULIN, VE
VOSTROKNUTOVA, ZN
TSVETKOV, EN
[J]. RUSSIAN CHEMICAL BULLETIN, 1993, 42 (03) : 472 - 477
[10] ORGANIC PHOSPHORUS-COMPOUNDS .112. REACTIVITY AND SELECTIVITY OF VINYLPHOSPHONIUM SALTS AND VINYLPHOSPHINE OXIDES COMPARED TO NUCLEOPHILES
HORNER, L
LINDEL, H
[J]. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1984, 20 (02): : 161 - 164

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