Aldehyde-decorated 2,2′-bipyridine and 2,2′:6′,2"-terpyridine ruthenium(II) complexes: Convenient scaffolds for supramolecular chemistry

被引：4

作者：

Constable, Edwin C. ^{[1
]}

Redondo, Ana Hernandez ^{[1
]}

Housecroft, Catherine E. ^{[1
]}

Neuburger, Markus ^{[1
]}

机构：

[1] Univ Basel, Dept Chem, CH-4056 Basel, Switzerland

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2010年 / 13卷 / 01期

基金：

瑞士国家科学基金会;

关键词：

2,2 '-Bipyridine; 2,2 ':6 ',2 ''-Terpyridine; Aldehyde; Ruthenium; Structure; BUILDING-BLOCKS; SENSITIZERS;

D O I：

10.1016/j.inoche.2009.10.019

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new aldehyde-decorated tpy and bpy-containing ruthenium(II) complexes, [Ru(1)(bpy)(2)][PF6](2) and [Ru(1)(tpy)Cl][PF6] in which 1 is 5,5'-bis(4-formylphenyl)-2,2'-bipyridine, have been prepared and fully characterized. The packing in both solid state structures involves extensive O-aldehyde center dot center dot center dot HCpyridine contacts, but pi-stacking interactions are important only between [Ru(1)(tpy)Cl](+) cations. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：70 / 73

页数：4

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