Iridium-catalyzed benzylic C-H activation and functionalization of alkyl arenes

被引：17

作者：

Voutchkova, Adelina M. ^{[1
]}

Crabtree, Robert H. ^{[1
]}

机构：

[1] Yale Univ, Dept Chem, New Haven, CT 06520 USA

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2009年 / 312卷 / 1-2期

关键词：

Iridium; C-H functionalization; Heterogeneous catalysis; Imine; Amine; DEHYDROGENATIVE-COUPLING CDC; BOND ACTIVATION; NITROGEN ATOM; ARYLATION; ADJACENT; SP(2); MECHANISM; TETRAHYDROISOQUINOLINES; COMPLEXES; INSERTION;

D O I：

10.1016/j.molcata.2009.07.019

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A recyclable catalyst, Ir/C. gives C-H benzylic functionalization of simple arenes to afford aldehydes, esters, and imines. In the case of esters, an additive, Ag2CO3. acts as base and oxidant, while for imine formation no additive is necessary. In this latter case a double C-H activation is proposed. accompanied by loss of H-2. (C) 2009 Elsevier B.V. All rights reserved.

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页码：1 / 6

页数：6

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