Pd salen complex@CPGO as a convenient, effective heterogeneous catalyst for Suzuki-Miyaura and Heck-Mizoroki cross-coupling reactions

被引:16
作者
Ghabdian, Mahdieh [1 ]
Nasseri, Mohammad Ali [1 ]
Allahresani, Ali [1 ]
Motavallizadehkakhky, Alireza [2 ]
机构
[1] Univ Birjand, Fac Sci, Dept Chem, POB 97175-615, Birjand, Iran
[2] Islamic Azad Univ, Sch Sci, Dept Chem, Neyshabur Branch, POB 9318813-639, Neyshabur, Iran
关键词
Suzuki– Miyaura reaction; Heck– Mizoroki reaction; Pd(II) salen@CPGO nano catalyst; Heterogeneous catalyst; Recyclable catalyst;
D O I
10.1007/s11164-018-3455-4
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A Pd(II) Schiff base complex supported on graphene oxide nanosheets (Pd(II) salen@CPGO) has been synthesized and characterized by FT-IR, ICP-AES, XRD, SEM/EDX and TEM. The synthesized nanocatalyst has been found to be an efficient heterogeneous catalyst for Suzuki-Miyaura and Heck-Mizoroki coupling reactions. Pd(II) salen@CPGO could be separated and recovered easily from the reaction mixture and recycled several times without a discernible decrease in its catalytic activity. The construction of a solid sheet-supported Pd catalyst would be expected to be a promising system to perform heterogeneous catalytic reactions.
引用
收藏
页码:1713 / 1728
页数:16
相关论文
共 29 条
  • [1] Nanoparticulate palladium supported by covalently modified silicas: Synthesis, characterization, and application as catalysts for the Suzuki coupling of aryl halides
    Bedford, RB
    Singh, UG
    Walton, RI
    Williams, RT
    Davis, SA
    [J]. CHEMISTRY OF MATERIALS, 2005, 17 (04) : 701 - 707
  • [2] Microwave-assisted Sonogashira cross-coupling reaction catalyzed by Pd-MCM-41 under solvent-free conditions
    Chang, Wonghil
    Shin, Jihye
    Chae, GeumHee
    Jang, So Ra
    Ahn, Byoung Joon
    [J]. JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2013, 19 (03) : 739 - 743
  • [3] Mercaptopropyl-modified mesoporous silica: A remarkable support for the preparation of a reusable, heterogeneous palladium catalyst for coupling reactions
    Crudden, CM
    Sateesh, M
    Lewis, R
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (28) : 10045 - 10050
  • [4] Phosphinite-functionalized silica and hexagonal mesoporous silica containing palladium nanoparticles in Heck coupling reaction: synthesis, characterization, and catalytic activity
    Farjadian, Fatemeh
    Hosseini, Majid
    Ghasemi, Soheila
    Tamami, Bahman
    [J]. RSC ADVANCES, 2015, 5 (97): : 79976 - 79987
  • [5] Remarkable catalytic activity of [PdCl2(CH3CN)2] in Suzuki-Miyaura cross-coupling reaction in aqueous media under mild conditions
    Ganesamoorthy, S.
    Shanmugasundaram, K.
    Karvembu, R.
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2013, 371 : 118 - 124
  • [6] Graphene Oxide Catalyzed C-H Bond Activation: The Importance of Oxygen Functional Groups for Biaryl Construction
    Gao, Yongjun
    Tang, Pei
    Zhou, Hu
    Zhang, Wei
    Yang, Hanjun
    Yan, Ning
    Hu, Gang
    Mei, Donghai
    Wang, Jianguo
    Ma, Ding
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (09) : 3124 - 3128
  • [7] Suzuki, Stille and Heck cross-coupling reactions catalyzed by Fe3O4@PTA-Pd as a recyclable and efficient nanocatalyst in green solvents
    Ghorbani-Choghamarani, Arash
    Norouzi, Masoomeh
    [J]. NEW JOURNAL OF CHEMISTRY, 2016, 40 (07) : 6299 - 6307
  • [8] One-step synthesis of palladium/SBA-15 nanocomposites and its catalytic application
    Han, Peng
    Wang, Xiaomei
    Qiu, Xuepeng
    Ji, Xiangling
    Gao, Lianxun
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 272 (1-2) : 136 - 141
  • [9] PREPARATION OF GRAPHITIC OXIDE
    HUMMERS, WS
    OFFEMAN, RE
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) : 1339 - 1339
  • [10] Palladium supported on silica-chitosan hybrid material (Pd-CS@SiO2) for Suzuki-Miyaura and Mizoroki-Heck cross-coupling reactions
    Jadhav, Sanjay
    Kumbhar, Arjun
    Salunkhe, Rajashri
    [J]. APPLIED ORGANOMETALLIC CHEMISTRY, 2015, 29 (06) : 339 - 345