High-performance La0.5(Ba0.75Ca0.25)0.5Co0.8Fe0.2O3-δ cathode for proton-conducting solid oxide fuel cells

被引：60

作者：

Xie, Dong ^{[1
]}

Li, Kai ^{[2
]}

Yang, Jun ^{[3
]}

Yan, Dong ^{[1
]}

Jia, Lichao ^{[1
]}

Chi, Bo ^{[1
]}

Pu, Jian ^{[1
]}

Li, Jian ^{[1
]}

机构：

[1] Huazhong Univ Sci & Technol, State Key Lab Mat Proc & Die & Mould Technol, Sch Mat Sci & Engn, Ctr Fuel Cell Innovat, Wuhan 430074, Peoples R China

[2] Xian Shiyou Univ, Sch Mat Sci & Engn, Xian 710065, Peoples R China

[3] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Peoples R China

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2021年 / 46卷 / 15期

基金：

中国国家自然科学基金;

关键词：

Proton-conducting solid oxide fuel cell; Cathode; Oxygen reduction reaction; Electrochemical performance; Long-term stability;

D O I：

10.1016/j.ijhydene.2020.01.014

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

La-0.5(Ba0.75Ca0.25)(0.5)Co0.8Fe0.2O3-delta, a simple perovskite cathode material with high electrical conductivity (940 S cm(-1) at 600 degrees C) and impressive surface catalytic activity, was prepared and used in proton-conducting solid oxide fuel cells. As its thermal expansion coefficient is higher than that of the electrolyte material BaZr0.1Ce 0.7Y0.1Yb0.1O3-delta, they were combined and used as a composite cathode. The crystal structure, chemical compatibility, electrical conductivity, cell performance, and the oxygen reduction reaction of the cathode material were explored, and we found that the single fuel cell developed with the composite cathode achieved excellent electrochemical performance, with both a low polarization resistance and high peak power density (0.044 Omega cm(2) and 1102 mW cm(-2 )at 750 degrees C, respectively). Outstanding stability was also achieved, as indicated by a long-term 100-h test. Additionally, the rate-limiting steps of the oxygen reduction reaction were the oxygen adsorption, dissociation, and diffusion processes. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

引用

页码：10007 / 10014

页数：8

共 60 条

[1] Characterisation of composite SOFC cathodes using electrochemical impedance spectroscopy. Analysis of Pt/YSZ and LSM/YSZ electrodes [J].