Crystal structure of [UO2SeO4{(CH3)2NCONH2}2(H2O)] • H2O

被引：0

作者：

Mit'kovskaya, EV

Demchenko, EA

Mikhailov, YN

Gorbunova, YE

Serezhkina, LB

Serezhkin, VN

机构：

[1] Samara State Univ, Samara 443011, Russia

[2] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2002年 / 47卷 / 09期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An X-ray single-crystal structure experiment was carried out on UO2SeO4 . 2(CH3)(2)NCONH2 . 2H(2)O (compound I). Compound I crystallizes in monoclinic system, space group C2/c, Z = 8, a = 18.758 Angstrom b = 16.571 Angstrom, c = 12.786 Angstrom, beta = 121.44degrees. The crystals of compound I are structurally built of [UO2SeO4{(CH3)(2)NCONH2)(2)(H2O)] . H2O dimers, which are formed through selenato bridges and linked into a three-dimensional network through the O(N)-H...O hydrogen-bond array. Compound I belongs to the AB(2)M(3)(1) (A = UO22+) crystallochemical family of uranyl complexes.

引用

页码：1306 / 1310

页数：5