Highly sensitive and selective trimethylamine sensors based on WO3 nanorods decorated with Au nanoparticles

被引:35
作者
Liu, Lu [1 ]
Song, Peng [1 ]
Yang, Zhongxi [1 ]
Wang, Qi [1 ]
机构
[1] Univ Jinan, Shandong Prov Key Lab Preparat & Measurement Bldg, Sch Mat Sci & Engn, Jinan 250022, Peoples R China
基金
中国国家自然科学基金;
关键词
WO3; nanorods; Au nanoparticles; Nanocomposites; Gas sensors; Trimethylamine; GAS-SENSING PROPERTIES; OXIDE NANOSTRUCTURES; LOW-TEMPERATURE; THIN-FILMS; PERFORMANCE; FABRICATION; ETHANOL; MICROSPHERES; NANONEEDLES; ADSORPTION;
D O I
10.1016/j.physe.2017.03.025
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
One-dimensional tungsten oxide (WO3) gas sensing materials have been widely used for the detection of trimethylamine (TMA) gas. Furthermore, it is believed that an effective method to improve the gas sensing performance is to introduce noble metals into sensing materials. In this work, a novel gas sensing material was prepared by decorating Au nanoparticles on WO3 nanorods. Based on field emission scanning electron microscopy (FESEM/EDS), X-ray diffraction (XRD), and transmission electron microscopy (TEM), the morphology and microstructure of as-prepared samples were characterized. Results show that Au nanoparticles with diameter of 13-15 nm are loaded on the surface of WO3 nanorods with length of about 1-2 pm and width of 50-80 nm. Gas sensing tests reveal that the Au@WO3 sensor has remarkably enhanced response to TMA gas compared with pure WO3 (n)anorods. In addition, and the gas sensing mechanism has been investigated based on the experimental results. The superior sensing features indicate the present Au@WO3 nanocomposites are promising for gas sensors, which can be used in the detection of the trimethylamine gas and this work provides insights and strategies for the fabrication of sensing materials.
引用
收藏
页码:109 / 115
页数:7
相关论文
共 53 条
[1]   Controlled growth and characterization of tungsten oxide nanowires using thermal evaporation of WO3 powder [J].
Baek, Yunho ;
Yong, Kijung .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (03) :1213-1218
[2]   Conduction model of metal oxide gas sensors [J].
Barsan, N ;
Weimar, U .
JOURNAL OF ELECTROCERAMICS, 2001, 7 (03) :143-167
[3]   Low-temperature and highly selective NO-sensing performance of WO3 nanoplates decorated with silver nanoparticles [J].
Chen, Deliang ;
Yin, Li ;
Ge, Lianfang ;
Fan, Bingbing ;
Zhang, Rui ;
Sun, Jing ;
Shao, Guosheng .
SENSORS AND ACTUATORS B-CHEMICAL, 2013, 185 :445-455
[4]   Ultraselective and ultrasensitive detection of trimethylamine using MoO3 nanoplates prepared by ultrasonic spray pyrolysis [J].
Cho, Yoon Ho ;
Ko, You Na ;
Kang, Yun Chan ;
Kim, Il-Doo ;
Lee, Jong-Heun .
SENSORS AND ACTUATORS B-CHEMICAL, 2014, 195 :189-196
[5]   Highly selective and sensitive detection of trimethylamine using WO3 hollow spheres prepared by ultrasonic spray pyrolysis [J].
Cho, Yoon Ho ;
Kang, Yun Chan ;
Lee, Jong-Heun .
SENSORS AND ACTUATORS B-CHEMICAL, 2013, 176 :971-977
[6]   One-Dimensional Oxide Nanostructures as Gas-Sensing Materials: Review and Issues [J].
Choi, Kyoung Jin ;
Jang, Ho Won .
SENSORS, 2010, 10 (04) :4083-4099
[7]   Macroporous WO3 Thin Films Active in NH3 Sensing: Role of the Hosted Cr Isolated Centers and Pt Nanoclusters [J].
D'Arienzo, Massimiliano ;
Armelao, Lidia ;
Mari, Claudio Maria ;
Polizzi, Stefano ;
Ruffo, Riccardo ;
Scotti, Roberto ;
Morazzoni, Franca .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (14) :5296-5304
[8]   Synthesis, characterization, and hydrogen gas sensing properties of AuNs-catalyzed ZnO sputtered thin films [J].
Drmosh, Q. A. ;
Yamani, Z. H. .
APPLIED SURFACE SCIENCE, 2016, 375 :57-64
[9]   Metal Oxide Semi-Conductor Gas Sensors in Environmental Monitoring [J].
Fine, George F. ;
Cavanagh, Leon M. ;
Afonja, Ayo ;
Binions, Russell .
SENSORS, 2010, 10 (06) :5469-5502