A room temperature structure for anhydrous lead (II) decanoate

被引：21

作者：

Ellis, HA ^{[1
]}

White, NA

Hassan, I

Ahmad, R

机构：

[1] Univ W Indies, Dept Chem, Kingston 7, Jamaica

[2] Univ W Indies, Dept Geol, Kingston 7, Jamaica

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2002年 / 642卷 / 1-3期

关键词：

lead (II) decanoate; X-ray diffraction; IR spectroscopy; polarizing light microscopy;

D O I：

10.1016/S0022-2860(02)00386-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The room temperature structure of anhydrous lead (II) decanoate has been studied using X-ray diffraction, infrared spectroscopy and polarizing light microscopy. A triclinic unit cell with dimensions: a = 8.529 (3), b = 11.207 (4), c = 28.451 (2) Angstrom; a = 83.814 (2), beta = 88.971 (2), gamma = 65.143 (3); Z = 4, M = 549.2 g mol(-1), D-c = 1.50 (6), D-m = 1.68 (2) is indicated. Infrared and powder diffraction data point to a structure containing both bidentate bonding and carboxylate bridging around, possibly eight coordinated lead. A bilayer arrangement of chains at an average 68degrees to planes containing Pb2+ ions is proposed. Each molecule is situated at the comers and center of the unit cell with possibly P (1) over bar symmetry as is the case for copper (II) decanoate. (C) 2002 Published by Elsevier Science B.V.

引用

页码：71 / 76

页数：6

共 24 条

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