Synthetically tailored excited states: Phosphorescent, cyclometalated iridium(III) complexes and their applications

被引:715
作者
Lowry, Michael S. [1 ]
Bernhard, Stefan [1 ]
机构
[1] Princeton Univ, Dept Chem, Princeton, NJ 08544 USA
基金
美国国家科学基金会;
关键词
iridium; luminescence; OLEDs; photochemistry; structure-property relationships;
D O I
10.1002/chem.200600618
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Phosphorescent iridium(III) complexes are being widely explored for their utility in diverse photophysical applications. The performance of these materials in such roles depends heavily on their excited-state properties, which can be tuned through ligand and substituent effects. This concept article focuses on methods for synthetically tailoring the properties of bis-cyclometalated iridium(III) materials, and explores the factors governing the nature of their lowest excited state.
引用
收藏
页码:7970 / 7977
页数:8
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