Hydroxyl groups in phosphosilicate glass for optical fibers

被引：1

作者：

Plotnichenko, VG ^{[1
]}

Sokolov, VO ^{[1
]}

Kryukova, EB ^{[1
]}

Dianov, EM ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Gen Phys, Res Ctr Fiber Opt, Moscow 117756, Russia

来源：

INORGANIC MATERIALS | 2000年 / 36卷 / 04期

关键词：

Optical Fiber; Silica Glass; Phosphorus Atom; Vibration Spectrum; P205 Concentration;

D O I：

10.1007/BF02758092

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

To gain insight into the local environment of impurity hydroxyl groups in phosphosilicate glass and determine its signatures in the vibration spectrum, the IR absorption spectra of phosphosilicate glasses containing up to 20 mol % P2O5 were analyzed. The interaction of hydroxyl groups with phosphorus-containing centers was studied with the use of a cluster model and the PM3 and MNDO quantum-chemical methods. The observed changes in the OH-stretching region of the absorption spectrum were interpreted using the modeling results.

引用

页码：411 / 417

页数：7

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