Bis{N-[bis(pyrrolidin-1-yl)phosphoryl]-2,2,2-trichloroacetamide}dinitratodioxidouranium(VI)

被引：10

作者：

Znovjyak, Kateryna O. ^{[1
]}

Ovchynnikov, Vladimir A. ^{[1
]}

Moroz, Olesia V. ^{[1
]}

Shishkina, Svitlana V. ^{[2
]}

Amirkhanov, Vladimir M. ^{[1
]}

机构：

[1] Kyiv Natl Taras Shevchenko Univ, Dept Chem, UA-01601 Kiev, Ukraine

[2] Natl Acad Sci Ukraine, STC Inst Single Crystals, UA-61001 Kharkov, Ukraine

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

关键词：

Data-to-parameter ratio = 21.2; Disorder in main residue; Mean σ(C-C) = 0.009 Å; R factor = 0.034; Single-crystal X-ray study; T = 293 K; WR factor = 0.085;

D O I：

10.1107/S1600536810006422

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The crystal structure of the title compound, [U(NO3)(2)O-2-(C10H17Cl3N3O2P)(2)], is composed of centrosymmetric [UO2( L) 2(NO3) 2] molecules {L is N-[bis(pyrrolidin-1-yl) phosphoryl]-2,2,2-trichloroacetamide, C10H17Cl3N3O2P}. The U VI ion, located on an inversion center, is eight-coordinated with axial oxido ligands and six equatorial oxygen atoms of the phosphoryl and nitrate groups in a slightly distorted hexagonal-bipyramidal geometry. One of the pyrrolidine fragments in the ligand is disordered over two conformation (occupancy ratio 0.58:0.42). Intramolecular N-H center dot center dot center dot O hydrogen bonds between the amine and nitrate groups are found.

引用

页码：M322 / U3749

页数：10

共 8 条

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