Co-Solvent Free Electrochemical Synthesis of Biodiesel Using Graphite Electrode and Waste Concrete Heterogeneous Catalyst: Optimization of Biodiesel Yield

被引：5

作者：

Wicaksono, Wiyogo Prio ^{[1
,2
]}

Jati, Sekar Asmara ^{[1
,2
]}

Yanti, Ika ^{[1
]}

Jiwanti, Prastika Krisma ^{[3
]}

机构：

[1] Univ Islam Indonesia, Dept Chem, Fac Math & Nat Sci, Jl Kaliurang KM 14-5, Yogyakarta 55584, Indonesia

[2] Univ Islam Indonesia, Res Ctr Mat & Electrochem, Fac Math & Nat Sci, Jl Kaliurang KM 14-5, Yogyakarta 55584, Indonesia

[3] Univ Airlangga, Fac Adv Technol & Multidiscipline, Nanotechnol Engn, Kampus C Univ Airlangga, Surabaya 60115, Indonesia

来源：

BULLETIN OF CHEMICAL REACTION ENGINEERING AND CATALYSIS | 2021年 / 16卷 / 01期

关键词：

Electrochemical Synthesis; Biodiesel; Waste Concrete; Heterogeneous Catalyst; Waste Cooking Oil; COOKING OIL; TRANSESTERIFICATION; CAO;

D O I：

10.9767/bcrec.16.1.10310.179-187

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

This study optimized a co-solvent free electrochemical method for biodiesel synthesis using graphite electrode and waste concrete heterogeneous catalyst. Various parameters were evaluated, including: applied voltage (9.6, 14.4, 19.2 V), catalyst particle size uniformity (unfiltered and filtered with 150 mesh), and reaction time (15, 30, 120, 240 min). The results obtained 100% FAME content and 78.51% of biodiesel yield that were achieved at 14.4 V within 30 min using filtered catalyst and cooking oil feedstock. However, a slight decline was observed with the use of waste cooking oil. This optimized method offers a reliable and simple condition for mass biodiesel production. Copyright (c) 2021 by Authors, Published by BCREC Group.

引用

页码：179 / 187

页数：9

共 28 条

[1] Electro-Catalytic Biodiesel Production from Canola Oil in Methanolic and Ethanolic Solutions with Low-Cost Stainless Steel and Hybrid Ion-Exchange Resin Grafted Electrodes [J].

Allioux, Francois-Marie ;

Holland, Brendan J. ;

Kong, Lingxue ;

Dumee, Ludovic F. .

FRONTIERS IN MATERIALS, 2017, 4

[2] Eco-friendly synthesis of biodiesel from WCO by using electrolysis technique with graphite electrodes [J].

Asl, Mohammad Abdollahi ;

Tahvildari, Kambiz ;

Bigdeli, Tania .

FUEL, 2020, 270

[3]

Badan Standarisasi Nasional, 2015, Standar Nasional Indonesia 7182:2015 Biodiesel, P1

[4] Performance of calcium oxide as a heterogeneous catalyst in biodiesel production: A review [J].

Boey, Peng-Lim ;

Maniam, Gaanty Pragas ;

Abd Hamid, Shafida .

CHEMICAL ENGINEERING JOURNAL, 2011, 168 (01) :15-22

[5] Chemistry of deep-fat frying oils [J].

Choe, E. ;

Min, D. B. .

JOURNAL OF FOOD SCIENCE, 2007, 72 (05) :R77-R86

[6]

Dumesic J.A., 2008, HDB HETEROGENEOUS CA, V2nd, DOI [10.1002/9783527610044, DOI 10.1002/9783527610044]

[7] Use of ZrO2 supported on bamboo leaf ash as a heterogeneous catalyst in microwave-assisted biodiesel conversion [J].

Fatimah, Is ;

Rubiyanto, Dwiarso ;

Taushiyah, Ana ;

Najah, Fitri Badriatun ;

Azmi, Ulil ;

Sim, Yoke-Leng .

SUSTAINABLE CHEMISTRY AND PHARMACY, 2019, 12

[8] Trans-esterification of waste cooking oil with methanol by electrolysis process using KOH [J].

Fereidooni, Leila ;

Tahvildari, Kambiz ;

Mehrpooya, Mehdi .

RENEWABLE ENERGY, 2018, 116 :183-193

[9] Experimental assessment of electrolysis method in production of biodiesel from waste cooking oil using zeolite/chitosan catalyst with a focus on waste biorefinery [J].

Fereidooni, Leila ;

Mehrpooya, Mehdi .

ENERGY CONVERSION AND MANAGEMENT, 2017, 147 :145-154

[10] Synthesis of biodiesel fuel using an electrolysis method [J].

Guan, Guoqing ;

Kusakabe, Katsuki .

CHEMICAL ENGINEERING JOURNAL, 2009, 153 (1-3) :159-163

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