Trifluoromethylthiodediazoniation: a simple, efficient route to trifluoromethyl aryl sulfides

被引：101

作者：

Adams, DJ ^{[1
]}

Goddard, A ^{[1
]}

Clark, JH ^{[1
]}

Macquarrie, DJ ^{[1
]}

机构：

[1] Univ York, Dept Chem, Clean Technol Ctr, York YO10 5DD, N Yorkshire, England

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 11期

关键词：

D O I：

10.1039/b002560g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Copper(I) trifluoromethanethiolate reacts with a range of diazonium salts containing electron-withdrawing groups to give the corresponding trifluoromethyl aryl sulfides in high yield; it is also possible to carry out the diazotisation and trifluoromethylthiolation in one pot directly from the anilines.

引用

页码：987 / 988

页数：2

共 18 条

[1] A new simple access to trifluoromethyl thioethers or selenoethers from trifluoromethyl trimethylsilane and disulfides or diselenides
Billard, T
Langlois, BR
[J]. TETRAHEDRON LETTERS, 1996, 37 (38) : 6865 - 6868
[2] Clark J. H., 1997, AROMATIC FLUORINATIO
[3] THE INTRODUCTION OF SCF3 INTO AROMATIC SUBSTRATES USING CUSCF3 AND ALUMINA-SUPPORTED CUSCF3
CLARK, JH
JONES, CW
KYBETT, AP
MCCLINTON, MA
MILLER, JM
BISHOP, D
BLADE, RJ
[J]. JOURNAL OF FLUORINE CHEMISTRY, 1990, 48 (02) : 249 - 255
[4] NOVEL SYNTHESIS OF TRIFLUOROMETHYLTHIOACETIC ACID
DEMARINIS, RM
BRYAN, WM
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1977, 42 (11) : 2024 - 2025
[5] ALKYL NITRITE METAL HALIDE DEAMINATION REACTIONS .2. SUBSTITUTIVE DEAMINATION OF ARYLAMINES BY ALKYL NITRITES AND COPPER(II) HALIDES - DIRECT AND REMARKABLY EFFICIENT CONVERSION OF ARYLAMINES TO ARYL HALIDES
DOYLE, MP
SIEGFRIED, B
DELLARIA, JF
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1977, 42 (14) : 2426 - 2431
[6] Filler R., 1979, ORGANOFLUORINE CHEM
[7] APROTIC DIAZOTIZATION OF ANILINE IN PRESENCE OF IODINE
FRIEDMAN, L
CHLEBOWS.JF
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1968, 33 (04) : 1636 - &
[8] Decomposition reactions of the aromatic diazo-compounds Part VII Some reactions of diazonium chlorides with esters and nitriles
Hanby, WE
Waters, WA
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1939, : 1792 - 1795
[9] TRIFLUOROMETHYLTHIOALKANES -OLEFINS AND -ACETYLENES
HARRIS, JF
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1967, 32 (07) : 2063 - &
[10] HEGARTY AF, 1978, CHEM DIAZONIUM DIAZO

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