Mesoporous single-crystal-like TiO2 mesocages threaded with carbon nanotubes for high-performance electrochemical energy storage

被引:72
作者
Peng, Yiting [1 ]
Le, Zaiyuan [2 ]
Wen, Meicheng [3 ,4 ]
Zhang, Dieqing [3 ,4 ]
Chen, Zheng [2 ]
Wu, Hao Bin [2 ]
Li, Hexing [1 ,3 ,4 ]
Lu, Yunfeng [2 ]
机构
[1] Shanghai Univ Elect Power, Coll Environm & Chem Engn, Shanghai Key Lab Mat Protect & Adv Mat Elect Powe, Shanghai 200090, Peoples R China
[2] Univ Calif Los Angeles, Dept Chem & Biomol Engn, Los Angeles, CA 90095 USA
[3] Shanghai Normal Univ, Dept Chem, Key Lab Resource Chem, Educ Minist, Shanghai 200234, Peoples R China
[4] Shanghai Normal Univ, Dept Chem, Shanghai Key Lab Rare Earth Funct Mat, Shanghai 200234, Peoples R China
关键词
Nanocomposite; TiO2; Single-crystalline; Carbon nanotubes; Energy storage; LITHIUM-ION BATTERIES; ANODE MATERIALS; NANOCRYSTALS; NANOSTRUCTURES; ARCHITECTURES; MICROSPHERES; ELECTRODE; SPHERES; OXIDE;
D O I
10.1016/j.nanoen.2017.03.003
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel nanocomposite based on mesoporous single-crystalline TiO2 particles (TiO2 mesocages) threaded with carbon nanotubes (CNTs) has been successfully synthesized via a facile solvothermal method. The unique hybrid architecture endows the nanocomposite with facile ion and electron transport pathways, abundant active surface sites and high structure robustness. As a result, remarkable electrochemical lithium storage properties in terms of high capacity, excellent rate capability and ultra-stable long-term cycling performance have been achieved by the CNTs-threaded TiO2 mesocages.
引用
收藏
页码:44 / 51
页数:8
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