On the design of ultrafast shutters for time-resolved synchrotron experiments

被引:24
作者
Gembicky, Milan [1 ]
Coppens, Philip [1 ]
机构
[1] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA
关键词
time-resolved experimentation; ultrafast pulse selector; synchrotron science; synchrotron fill pattern;
D O I
10.1107/S0909049506041835
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
A comprehensive treatment of the limitations and possibilities for single-pulse selection in synchrotron operating modes with similar to 150 ns bunch separation, as occurs in the standard operating mode at the Advanced Photon Source, is presented. It is shown that the strength of available materials and allowable kinetic energy build-up limit single-bunch selection for this separation to sample sizes of similar to 100 mu m, and that for minimization of kinetic energy build-up it is preferable to increase the r.p.m. within physically acceptable limits rather than increase the disc radius to obtain a desirable peripheral speed. A slight modification of the equal-bunch spacing standard fill patterns is proposed that allows use of samples as large as 500 mu m. The corresponding peripheral speed of the chopper wheel is similar to 600 m s(-1), which is within the limits of high-strength titanium alloys. For smaller samples, peripheral speeds are proportionally lower. Versatility can be achieved with interchangeable chopper wheels and the use of different orientations of the rotation axis relative to the X-ray beam, which opens the possibility of larger, rather than one-of-a-kind, production runs.
引用
收藏
页码:133 / 137
页数:5
相关论文
共 22 条
[1]   Chromophore conformation and the evolution of tertiary structural changes in photoactive yellow protein [J].
Anderson, S ;
Srajer, V ;
Pahl, R ;
Rajagopal, S ;
Schotte, F ;
Anfinrud, P ;
Wulff, M ;
Moffat, K .
STRUCTURE, 2004, 12 (06) :1039-1045
[2]   MAGNETICALLY SUSPENDED CROSS-CORRELATION CHOPPER IN MOLECULAR BEAM-SURFACE EXPERIMENTS [J].
COMSA, G ;
DAVID, R ;
SCHUMACHER, BJ .
REVIEW OF SCIENTIFIC INSTRUMENTS, 1981, 52 (06) :789-797
[3]   The structure of short-lived excited states of molecular complexes by time-resolved X-ray diffraction [J].
Coppens, P ;
Vorontsov, II ;
Graber, T ;
Gembicky, M ;
Kovalevsky, AY .
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2005, 61 :162-172
[4]   Introductory Lecture - Time-resolved chemistry at atomic resolution [J].
Coppens, P ;
Novozhilova, IV .
FARADAY DISCUSSIONS, 2003, 122 :1-11
[5]   A fast mechanical shutter for submicrosecond time-resolved synchrotron experiments [J].
Gembicky, M ;
Oss, D ;
Fuchs, R ;
Coppens, P .
JOURNAL OF SYNCHROTRON RADIATION, 2005, 12 :665-669
[6]  
Hearn Edwin John, 1997, MECH MATER, P117, DOI [10.1016/B978-075063266-9/50005-6, DOI 10.1016/B978-075063266-9/50005-6]
[7]  
Helliwell J. R., 1997, Time-Resolved Diffraction
[8]   Extraction of single bunches of synchrotron radiation from storage rings with an X-ray chopper based on a rotating mirror [J].
Kosciesza, D ;
Bartunik, HD .
JOURNAL OF SYNCHROTRON RADIATION, 1999, 6 :947-952
[9]   AN ULTRAFAST MECHANICAL SHUTTER FOR X-RAYS [J].
LEGRAND, AD ;
SCHILDKAMP, W ;
BLANK, B .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT, 1989, 275 (02) :442-446
[10]   A synchronized rotating crystal x-ray beam chopper [J].
McPherson, A ;
Lee, WK ;
Mills, DM .
REVIEW OF SCIENTIFIC INSTRUMENTS, 2002, 73 (08) :2852-2855