Functional and Tuneable Amino Acid Polymers Prepared by RAFT Polymerization

被引：31

作者：

Evans, Amanda C. ^{[1
]}

Skey, Jared ^{[1
,2
]}

Wright, Megan ^{[1
]}

Qu, Wenjun ^{[1
]}

Ondeck, Courtney ^{[1
]}

Longbottom, Deborah A. ^{[1
]}

O'Reilly, Rachel K. ^{[1
,2
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1LW, England

[2] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2009年 / 47卷 / 24期

基金：

英国工程与自然科学研究理事会;

关键词：

L-proline copolymers; organocatalysis; polystyrene; reversible addition-fragmentation chain transfer (RAFT); trithiocarbonate; FRAGMENTATION CHAIN TRANSFER; ASYMMETRIC-ALDOL-REACTION; LIVING RADICAL POLYMERIZATION; ORGANOCATALYTIC CONJUGATE ADDITION; WATER-SOLUBLE (CO)POLYMERS; L-PROLINE; SUPPORTED PROLINE; BLOCK-COPOLYMERS; ENANTIOSELECTIVE ALDOL; CHIROPTICAL PROPERTIES;

D O I：

10.1002/pola.23721

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We report the application of reversible addition-fragmentation chain transfer polymerization using a novel chain transfer agent toward the synthesis of a variety of copolymers containing proline-derived monomeric units. This methodology enables ready access to a number of polymeric species with narrow molecular weight distributions, reliable functional unit incorporations, and high conversions. The methodology is also a facile approach to novel copolymeric species incorporating amino, acids, which possess unique material properties and the potential for further organocatalytic application. (C) 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47:6814-6826, 2009

引用

页码：6814 / 6826

页数：13

共 50 条

[41] Ideal Molecular Weight Distributions of Multiblock Copolymers Prepared via RAFT Polymerization [J].

Ebeling, Bastian ;

Eggers, Martin ;

Vana, Philipp .

MACROMOLECULES, 2010, 43 (24) :10283-10290

[42] An Arm-First Approach to Cleavable MiktoArm Star Polymers by RAFT Polymerization [J].

Wei, Xiaohu ;

Moad, Graeme ;

Muir, Benjamin W. ;

Rizzardo, Ezio ;

Rosselgong, Julien ;

Yang, Wantai ;

Thang, San H. .

MACROMOLECULAR RAPID COMMUNICATIONS, 2014, 35 (08) :840-845

[43] Nonmigratory Poly(vinyl chloride)-block-polycaprolactone Plasticizers and Compatibilizers Prepared by Sequential RAFT and Ring-Opening Polymerization (RAFT-T-ROP) [J].

Sun, Zhonghe ;

Choi, Bonnie ;

Feng, Anchao ;

Moad, Graeme ;

Thang, San H. .

MACROMOLECULES, 2019, 52 (04) :1746-1756

[44] Epoxy-Functional Sterically Stabilized Diblock Copolymer Nanoparticles via RAFT Aqueous Emulsion Polymerization: Comparison of Two Synthetic Strategies [J].

Gyorgy, Csilla ;

Lovett, Joseph R. ;

Penfold, Nicholas J. W. ;

Armes, Steven P. .

MACROMOLECULAR RAPID COMMUNICATIONS, 2019, 40 (02)

[45] Zwitterionic polymer-grafted microspheres prepared by RAFT polymerization [J].

Kitano, Hiromi ;

Tokuwa, Ken-ichi ;

Ueno, Haruka ;

Li, Lifu ;

Saruwatari, Yoshiyuki .

COLLOID AND POLYMER SCIENCE, 2015, 293 (10) :2931-2939

[46] Functional end groups for polymers prepared using ring-opening metathesis polymerization [J].

Hilf, Stefan ;

Kilbinger, Andreas F. M. .

NATURE CHEMISTRY, 2009, 1 (07) :537-546

[47] Self-healing linear polymers based on RAFT polymerization [J].

Yao, Li ;

Yuan, Yan Chao ;

Rong, Min Zhi ;

Zhang, Ming Qiu .

POLYMER, 2011, 52 (14) :3137-3145

[48] Controlled Bimodal Molecular-Weight-Distribution Polymers: Facile Synthesis by RAFT Polymerization [J].

Qin, Jian ;

Zhang, Lifen ;

Jiang, Hongjuan ;

Zhu, Jian ;

Zhang, Zhengbiao ;

Zhang, Wei ;

Zhou, Nianchen ;

Cheng, Zhenping ;

Zhu, Xiulin .

CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18 (19) :6015-6021

[49] Synthesis and photoresponsive behavior of the high-Tg azobenzene polymers via RAFT polymerization [J].

Xue, Xiaoqiang ;

Zhu, Jian ;

Zhang, Zhengbiao ;

Zhou, Nianchen ;

Zhu, Xiulin .

REACTIVE & FUNCTIONAL POLYMERS, 2010, 70 (07) :456-462

[50] Tryptophan-Containing Block Copolymers Prepared by RAFT Polymerization: Synthesis, Self-Assembly, and Chiroptical and Sensing Properties [J].

Mori, Hideharu ;

Takahashi, Eri ;

Ishizuki, Ai ;

Nakabayashi, Kazuhiro .

MACROMOLECULES, 2013, 46 (16) :6451-6465

← 1 2 3 4 5 →