Functional and Tuneable Amino Acid Polymers Prepared by RAFT Polymerization

被引：31

作者：

Evans, Amanda C. ^{[1
]}

Skey, Jared ^{[1
,2
]}

Wright, Megan ^{[1
]}

Qu, Wenjun ^{[1
]}

Ondeck, Courtney ^{[1
]}

Longbottom, Deborah A. ^{[1
]}

O'Reilly, Rachel K. ^{[1
,2
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1LW, England

[2] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2009年 / 47卷 / 24期

基金：

英国工程与自然科学研究理事会;

关键词：

L-proline copolymers; organocatalysis; polystyrene; reversible addition-fragmentation chain transfer (RAFT); trithiocarbonate; FRAGMENTATION CHAIN TRANSFER; ASYMMETRIC-ALDOL-REACTION; LIVING RADICAL POLYMERIZATION; ORGANOCATALYTIC CONJUGATE ADDITION; WATER-SOLUBLE (CO)POLYMERS; L-PROLINE; SUPPORTED PROLINE; BLOCK-COPOLYMERS; ENANTIOSELECTIVE ALDOL; CHIROPTICAL PROPERTIES;

D O I：

10.1002/pola.23721

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We report the application of reversible addition-fragmentation chain transfer polymerization using a novel chain transfer agent toward the synthesis of a variety of copolymers containing proline-derived monomeric units. This methodology enables ready access to a number of polymeric species with narrow molecular weight distributions, reliable functional unit incorporations, and high conversions. The methodology is also a facile approach to novel copolymeric species incorporating amino, acids, which possess unique material properties and the potential for further organocatalytic application. (C) 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47:6814-6826, 2009

引用

页码：6814 / 6826

页数：13

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