Laser-induced time-resolved luminescence spectroscopy of Pb2+ in minerals

被引:17
作者
Gaft, M
Seigel, H
Panczer, G
Reisfeld, R
机构
[1] Open Univ Isreal, Dept Nat Sci, IL-61392 Tel Aviv, Israel
[2] Univ Toronto, Dept Phys, Toronto, ON M5S 1A7, Canada
[3] Univ Lyon 1, Phys Chem Luminescence Mat Lab, F-69622 Villeurbanne, France
[4] CNRS, IL-61392 Tel Aviv, Israel
[5] Hebrew Univ Jerusalem, Dept Inorgan & Analyt Chem, IL-91940 Jerusalem, Israel
关键词
time-resolved luminescence spectroscopy; Pb2+; minerals;
D O I
10.1127/0935-1221/2002/0014-1041
中图分类号
P57 [矿物学];
学科分类号
070901 ;
摘要
Natural and synthetic samples of hardystonite, hydrozincite, calcite and pyromorphite were investigated by laser-induced time-resolved luminescence spectroscopy at 50 K to ambient temperatures. Luminescent bands of Pb2+ can be resolved from similar bands caused by Ce3+ and Eu2+ by a combination of diagnostic differences in excitation spectra and lifetimes of luminescence as a function of temperature. The results indicate that Pb2+ is a more common luminescent activator in minerals than hitherto suspected.
引用
收藏
页码:1041 / 1048
页数:8
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