Flexible and Thermostable Graphene/SiC Nanowire Foam Composites with Tunable Electromagnetic Wave Absorption Properties

被引:357
作者
Han, Meikang [1 ]
Yin, Xiaowei [1 ]
Hou, Zexin [1 ]
Song, Changqing [1 ]
Li, Xinliang [1 ]
Zhang, Litong [1 ]
Cheng, Laifei [1 ]
机构
[1] Northwestern Polytech Univ, Sci & Technol Thermostruct Composite Mat Lab, Xian 710072, Peoples R China
基金
中国国家自然科学基金;
关键词
graphene; SiC; electromagnetic absorption; flexible; thermostable; PERFORMANCE MICROWAVE-ABSORPTION; BROAD-BAND; CARBON NANOTUBES; NANOCOMPOSITES; LIGHTWEIGHT; ULTRALIGHT; DISPERSION; OXIDE;
D O I
10.1021/acsami.7b00951
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Three-dimensional (3D) flexible foams consisting of reduced graphene oxides (rGO) and in situ grown SiC nanowires (NWs) were prepared using freeze-drying and carbothernial reduction processes. By means of incorporating SiC nanowires into rGO foams, both the thermostability and electromagnetic absorption of the composites were improved. it was demonstrated that rGO/SiC NW foams were thermoz. stable beyond similar to 630 degrees C (90% weight retention in air attnosphere). As expected, rGO/SiC NW foams in the poly(dimethylsiloxane) matrix achieved' effective absorption in the entire X-band (8.2-12.4 GHz) with a thinner thickness (3 mm) in comparison with those of the pure rGO foams. It is revealed that SiC nanowires with abundant stacking faults, twinning interfaces, arid bridged junctions play an important role in the enhanced electromagnetic absorption performance) in addition to the,contribution of interconnected graphene networks. Hierarchical rGO/SiC NW foams not only are efficient absorbers in the critical environments but also can be applied in photocatalytic and thermal -management fields.
引用
收藏
页码:11803 / 11810
页数:8
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