Enhanced photocatalysis performance of BiOCl/graphene modified via polyvinylpyrrolidone

被引:16
作者
Li, F. Q. [1 ]
Sun, B. H. [1 ,2 ]
Qin, Y. L. [1 ,2 ]
Liu, X. Y. [1 ,2 ]
Liu, Z. Y. [2 ]
Ni, D. R. [2 ]
Xiao, B. L. [2 ]
Ma, Z. Y. [2 ]
机构
[1] Shenyang Ligong Univ, Sch Sci, 6 Nanping Cent Rd, Shenyang 110159, Peoples R China
[2] Chinese Acad Sci, Inst Met Res, Shi Changxu Innovat Ctr Adv Mat, 72 Wenhua Rd, Shenyang 110016, Peoples R China
关键词
BiOCl; Graphene; Hydrothermal; Photocatalysis; ONE-STEP SYNTHESIS; BIOCL NANOSHEETS; EFFICIENT PHOTOCATALYST; DEGRADATION; LIGHT; RGO; NANOCOMPOSITE; COMPOSITES; NANORODS; AEROGEL;
D O I
10.1016/j.vacuum.2020.109857
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
With the aim to improve the photocatalytic property, BiOCl/graphene (BR) and BiOCl/graphene modified via polyvinylpyrrolidone (BRP) were prepared in a hydrothermal route. The obtained BRP sample showed the highest photocatalytic activity for the degradation of Methyl Orange (MO) under visible light illumination as compared to the pure BiOCl and BR samples. The results indicate that the degradation rate constant of the BR reached 0.04874 min(-1) as compared to the 0.03227 min(-1) for the pure BiOCl. It was found that the reduced graphene oxide (RGO) could uniformly load BiOCl, and the chemical bonding interface between RGO and BiOCl reduced the recombination of electron-hole pairs. Further, adding polyvinylpyrrolidone could refine the size of the BiOCl and increase the number of the BiOCl adhered onto the graphene surface, and thereby providing the highest efficient catalytic effect, with the degradation rate constant reaching 0.06205 min(-)(1).
引用
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页数:7
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共 39 条
[1]   A ruthenium and palladium bimetallic system superior to a rhodium co-catalyst for TiO2-photocatalyzed ring hydrogenation of aniline to cyclohexylamine [J].
Araki, Sakae ;
Nakanishi, Kousuke ;
Tanaka, Atsuhiro ;
Kominami, Hiroshi .
JOURNAL OF CATALYSIS, 2020, 389 :212-217
[2]   Reduced graphene oxide supported MnO2 nanorods as recyclable and efficient adsorptive photocatalysts for pollutants removal [J].
Chhabra, Tripti ;
Kumar, Ajay ;
Bahuguna, Ashish ;
Krishnan, Venkata .
VACUUM, 2019, 160 :333-346
[3]   Enhanced photocatalytic performance of RGO/Ag nanocomposites produced via a facile microwave irradiation for the degradation of Rhodamine B in aqueous solution [J].
Divya, K. S. ;
Chandran, Akash ;
Reethu, V. N. ;
Mathew, Suresh .
APPLIED SURFACE SCIENCE, 2018, 444 :811-818
[4]   X-ray photoelectron spectroscopy: Towards reliable binding energy referencing [J].
Greczynski, G. ;
Hultman, L. .
PROGRESS IN MATERIALS SCIENCE, 2020, 107
[5]   Reliable determination of chemical state in x-ray photoelectron spectroscopy based on sample-work-function referencing to adventitious carbon: Resolving the myth of apparent constant binding energy of the C 1s peak [J].
Greczynski, G. ;
Hultman, L. .
APPLIED SURFACE SCIENCE, 2018, 451 :99-103
[6]   Compromising Science by Ignorant Instrument Calibration-Need to Revisit Half a Century of Published XPS Data [J].
Greczynski, Grzegorz ;
Hultman, Lars .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (13) :5002-5006
[7]   C1s Peak of Adventitious Carbon Aligns to the Vacuum Level: Dire Consequences for Material's Bonding Assignment by Photoelectron Spectroscopy [J].
Greczynski, Grzegorz ;
Hultman, Lars .
CHEMPHYSCHEM, 2017, 18 (12) :1507-1512
[8]   Visible light photocatalytic activity induced by Rh(III) modification on the surface of BiOCl [J].
Hu, Jinli ;
Wu, Xin ;
Huang, Caijin ;
Fan, Wenjie ;
Qiu, Xiaoqing .
APPLIED SURFACE SCIENCE, 2016, 387 :45-50
[9]   Size-controlled BiOCl-RGO composites having enhanced photodegradative properties [J].
Kang, Suhee ;
Pawar, Rajendra C. ;
Pyo, Youngjun ;
Khare, Varsha ;
Lee, Caroline Sunyong .
JOURNAL OF EXPERIMENTAL NANOSCIENCE, 2016, 11 (04) :259-275
[10]   Hierarchical assembly of BiOCl nanosheets onto bicrystalline TiO2 nanofiber: Enhanced photocatalytic activity based on photoinduced interfacial charge transfer [J].
Li, Lu ;
Zhang, Mingyi ;
Liu, Ying ;
Zhang, Xitian .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2014, 435 :26-33