Activated carbon derived from coconut coir pith as high performance supercapacitor electrode material

被引:70
作者
Sesuk, T. [1 ]
Tammawat, P. [1 ]
Jivaganont, P. [1 ]
Somton, K. [1 ]
Limthongkul, P. [1 ]
Kobsiriphat, W. [1 ]
机构
[1] NSTDA, Natl Met & Mat Technol Ctr, Khlong Luang 12120, Pathum Thani, Thailand
关键词
Electrochemical capacitor; Supercapacitor; Biomass; Activated carbon; Coconut; POROUS CARBONS; BIOMASS; WASTE; ADSORPTION; CELLULOSE; ANIONS; LEAVES;
D O I
10.1016/j.est.2019.100910
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
In this study, activated carbons were synthesized from coconut coir pith, an inexpensive and abundant type of biomass in Thailand. The coconut coir pith was activated by a combined physical and chemical activation route, using NaOH-to-char ratios of 1:1, 2:1 and 3:1 by weight. A high surface area of 2056 m(2) g(-1) was achieved with NaOH-to-char weight ratio of 3:1. Using this activated carbon in a symmetrical cell with aqueous electrolyte, high capacitance values were achieved. The specific capacitance values obtained were 232.3 F g(-1) at 0.1 A g(-1) and 192.0 F g(-1) at 1 A g(-1). Long-term cycling tests at 0.5 A g(-1) showed 95.4% capacitance retention after 5000 cycles. The high specific capacitance was attributed to the high micropore volume. The superior rate capability was from the interconnected pore structure of the activated carbon which allowed for efficient ion transport.
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页数:9
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共 44 条
  • [1] Contribution of Cations and Anions of Aqueous Electrolytes to the Charge Stored at the Electric Electrolyte/Electrode Interface of Carbon-Based Supercapacitors
    Aldama, Ivan
    Barranco, Violeta
    Kunowsky, Mirko
    Ibanez, Joaquin
    Rojo, Jose M.
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2017, 121 (22) : 12053 - 12062
  • [2] Ash B, 2006, J SCI IND RES INDIA, V65, P1008
  • [3] Azais P., 2013, Supercapacitors Materials, Systems and Applications, P307, DOI [DOI 10.1002/9783527646661.CH10, 10.1002/9783527646661.ch10]
  • [4] Causes of supercapacitors ageing in organic electrolyte
    Azais, Philippe
    Duclaux, Laurent
    Florian, Pierre
    Massiot, Dominique
    Lillo-Rodenas, Maria-Angeles
    Linares-Solano, Angel
    Peres, Jean-Paul
    Jehoulet, Christophe
    Beguin, Frangois
    [J]. JOURNAL OF POWER SOURCES, 2007, 171 (02) : 1046 - 1053
  • [5] Amorphous Carbon Nanofibers and Their Activated Carbon Nanofibers as Supercapacitor Electrodes
    Barranco, V.
    Lillo-Rodenas, M. A.
    Linares-Solano, A.
    Oya, A.
    Pico, F.
    Ibanez, J.
    Agullo-Rueda, F.
    Amarilla, J. M.
    Rojo, J. M.
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (22) : 10302 - 10307
  • [6] 2-Steps KOH activation of rice straw: An efficient method for preparing high-performance activated carbons
    Basta, A. H.
    Fierro, V.
    Ei-Saied, H.
    Celzard, A.
    [J]. BIORESOURCE TECHNOLOGY, 2009, 100 (17) : 3941 - 3947
  • [7] Activated carbon made from cow dung as electrode material for electrochemical double layer capacitor
    Bhattacharjya, Dhrubajyoti
    Yu, Jong-Sung
    [J]. JOURNAL OF POWER SOURCES, 2014, 262 : 224 - 231
  • [8] CHEMICAL MODIFICATION OF CELLULOSE BY ACYLATION: APPLICATION TO ADSORPTION OF METHYLENE BLUE
    Bouhdadi, R.
    Benhadi, S.
    Molina, S.
    George, B.
    El Moussaouiti, M.
    Merlin, A.
    [J]. MADERAS-CIENCIA Y TECNOLOGIA, 2011, 13 (01): : 105 - 116
  • [9] Cagnon Benoit, 2009, Bioresour Technol, V100, P292, DOI 10.1016/j.biortech.2008.06.009
  • [10] Activated porous carbon prepared from paulownia flower for high performance supercapacitor electrodes
    Chang, Jiuli
    Gao, Zhiyong
    Wang, Xiaorui
    Wu, Dapeng
    Xu, Fang
    Wang, Xin
    Guo, Yuming
    Jiang, Kai
    [J]. ELECTROCHIMICA ACTA, 2015, 157 : 290 - 298