A novel palladium intramolecular diaryl ether formation

被引：18

作者：

Olivera, R ^{[1
]}

SanMartin, R ^{[1
]}

Domínguez, E ^{[1
]}

机构：

[1] Euskal Herrika Unibertsitatea, Kimika Organikoa Saila, Zientzi Fak, Bilbao 48080, Spain

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 22期

关键词：

D O I：

10.1016/S0040-4039(00)00622-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This paper presents an efficient methodology for the preparation of dibenzoxepino[4,5-d]pyrazoles using a novel intramolecular palladium catalyzed diaryl ether formation. The effect of different chelating ligand systems, along with the unusual coupling reaction of phenoxides with aryl iodides and non-activated aryl moieties are also reported. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：4357 / 4360

页数：4

共 29 条

[1] Central 5-HT2A and D-2 dopamine receptor occupancy after sublingual administration of ORG 5222 in healthy men [J].

Andree, B ;

Halldin, C ;

VrijmoeddeVries, M ;

Farde, L .

PSYCHOPHARMACOLOGY, 1997, 131 (04) :339-345

[2] Novel electron-rich bulky phosphine ligands facilitate the palladium-catalyzed preparation of diaryl ethers [J].

Aranyos, A ;

Old, DW ;

Kiyomori, A ;

Wolfe, JP ;

Sadighi, JP ;

Buchwald, SL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (18) :4369-4378

[3]

BISCHOFF S, 1992, NOVEL ANTIPSYCHOTIC DRUGS, P117

[4] Vancomycin CD and DE macrocyclization and atropisomerism studies [J].

Boger, DL ;

Castle, SL ;

Miyazaki, S ;

Wu, JH ;

Beresis, RT ;

Loiseleur, O .

JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (01) :70-80

[5]

Claghorn J, 1996, Prog Drug Res, V46, P243

[6] Total synthesis of (+/-)-O-methylclavizepine [J].

delaFuente, MC ;

Castedo, L ;

Dominguez, D .

TETRAHEDRON, 1996, 52 (13) :4917-4924

[7] A convenient one-pot preparative method for 4,5-diarylisoxazoles involving amine exchange reactions [J].

Dominguez, E ;

Ibeas, E ;

deMarigorta, EM ;

Palacios, JK ;

SanMartin, R .

JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (16) :5435-5439

[8]

Eastmond GC, 1998, SYNTHESIS-STUTTGART, P894

[9] Systematic variation of bidentate ligands used in aryl halide amination. Unexpected effects of steric, electronic, and geometric perturbations [J].

Hamann, BC ;

Hartwig, JF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (15) :3694-3703

[10]

Hartwig JF, 1998, ANGEW CHEM INT EDIT, V37, P2046, DOI 10.1002/(SICI)1521-3773(19980817)37:15<2046::AID-ANIE2046>3.0.CO

← 1 2 3 →