Chemistry of N-hydroxyguanidines:: Photo-sensitized oxygenation and reaction with nitric oxide

被引:0
|
作者
Kabasawa, H
Ikeno, M
Suzukawa, M
Higuchi, K
Yanagisawa, K
Seki, H
Tokunaga, T
Ishikawa, T
机构
[1] Chiba Univ, Grad Sch Pharmaceut Sci, Inage Ku, Chiba 2638522, Japan
[2] FIA Instruments Co Ltd, Kita 1140003, Japan
[3] Chiba Univ, Ctr Chem Anal, Inage Ku, Chiba 2638522, Japan
[4] Yamanouchi Pharmaceut Co Ltd, Inst Drug Discovery Res, Mol Chem Anal & Metab Labs, Tsukuba, Ibaraki 3058585, Japan
关键词
D O I
10.1002/1522-2675(200209)85:9<2636::AID-HLCA2636>3.0.CO;2-L
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The chemistry of N-hydroxyguanidines, focusing on photo-sensitized oxygenation and reaction with nitric oxide (NO), was examined. In the former reaction, a urea derivative wits obtained as the main product together with the generation of NO. On the other hand, in the latter case, oxidative nitrosation occurred under aerobic conditions to give a nitrosourea derivative. which wits also obtained from urea by the same treatment.
引用
收藏
页码:2636 / 2643
页数:8
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