Isotope effects in liquid water by infrared spectroscopy. III. H2O and D2O spectra from 6000 to 0 cm-1

被引:238
作者
Max, Jean-Joseph [1 ]
Chapados, Camille [1 ]
机构
[1] Univ Quebec, Dept Chim Biol, Trois Rivieres, PQ G9A 5H7, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
TEMPERATURE-DEPENDENCE; AQUEOUS-SOLUTIONS; IR SPECTROSCOPY; DIELECTRIC-RELAXATION; OPTICAL-CONSTANTS; FREQUENCY-RANGE; THZ; ACETONITRILE; INTENSITIES; SIMULATION;
D O I
10.1063/1.3258646
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The infrared spectra (IR) of pure liquid light (H2O) and heavy (D2O) water were obtained with attenuated total reflection (ATR) and transmission measurements in the mid-IR and far-IR. With these and with other values obtained from the literature, the real (n) and imaginary parts (k) of the refractive index were meticulously derived in the complete IR region from 6000 to 0 cm(-1). The reliability of the results resides in the critical comparison of our experimental data with that obtained from other laboratories and between calculated and experimental spectra, obtained by ATR and transmission techniques. The new optical properties (n and k) can now be used as standards for liquid H2O and D2O. To these we have added the water (H and D) absorption coefficients (K) that are derived from the k values. These can be used as references for spectra obtained by transmission with an absorbance intensity scale because they ate almost the same. (C) 2009 American Institute of Physics. [doi: 10.1063/1.3258646]
引用
收藏
页数:13
相关论文
共 41 条
  • [21] Densimetric Studies of Binary Solutions Involving H2O or D2O as a Solute in Dimethylsulfoxide at Temperatures from (293.15 to 328.15) K and Atmospheric Pressure
    Ivanov, Evgeniy V.
    Lebedeva, Elena Yu
    Abrosimov, Vladimir K.
    Ivanova, Nadezhda G.
    JOURNAL OF SOLUTION CHEMISTRY, 2012, 41 (08) : 1311 - 1333
  • [22] Measurement of positions, intensities and self-broadening line shape parameters of H2O lines in the spectral ranges 1850-2280 cm-1 and 2390-4000 cm-1
    Loos, J.
    Birk, M.
    Wagner, G.
    JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER, 2017, 203 : 119 - 132
  • [23] Raman and NMR spectroscopy study of liquid crystalline ionogel phase in ionic liquid/H2O mixtures: The states of water
    Aleksa, V.
    Kausteklis, J.
    Klimavicius, V.
    Gdaniec, Z.
    Balevicius, V.
    JOURNAL OF MOLECULAR STRUCTURE, 2011, 993 (1-3) : 91 - 96
  • [24] Increasing correlation length in bulk supercooled H2O, D2O, and NaCl solution determined from small angle x-ray scattering
    Huang, Congcong
    Weiss, T. M.
    Nordlund, D.
    Wikfeldt, K. T.
    Pettersson, L. G. M.
    Nilsson, A.
    JOURNAL OF CHEMICAL PHYSICS, 2010, 133 (13)
  • [25] Infrared Spectroscopy of Hydrated Bisulfate Anion Clusters: HSO4-(H2O)1-16
    Yacovitch, Tara I.
    Wende, Torsten
    Jiang, Ling
    Heine, Nadja
    Meijer, Gerard
    Neumark, Daniel M.
    Asmis, Knut R.
    JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2011, 2 (17): : 2135 - 2140
  • [26] Infrared Spectroscopy of Small Protonated Water Clusters, H+(H2O)n (n=2-5): Isomers, Argon Tagging, and Deuteration
    Douberly, G. E.
    Walters, R. S.
    Cui, J.
    Jordan, K. D.
    Duncan, M. A.
    JOURNAL OF PHYSICAL CHEMISTRY A, 2010, 114 (13) : 4570 - 4579
  • [27] Second ionization constant of sulfuric acid in H2O and D2O from 150 to 300 °C at p=11.5 MPa using flow AC conductivity
    Conrad, Jacy K.
    Arcis, Hugues
    Ferguson, Jane P.
    Tremaine, Peter R.
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2023, 25 (03) : 1659 - 1676
  • [28] D2O-H2O solvent isotope effects on the enthalpy of 1,3-dimethylpropyleneurea hydration at temperatures from (278.15 to 313.15) K and atmospheric pressure
    Batov, Dmitriy V.
    Ivanov, Evgeniy V.
    THERMOCHIMICA ACTA, 2011, 514 (1-2) : 16 - 21
  • [29] D2O-H2O solvent isotope effects on the enthalpy of 1,1,3,3-tetramethyl-2-thiourea hydration at temperatures from (278.15 to 313.15) K and ambient pressure
    Ivanov, Evgeniy V.
    Batov, Dmitriy V.
    Abrosimov, V. K.
    THERMOCHIMICA ACTA, 2014, 590 : 206 - 209
  • [30] Water as a solute in aprotic dipolar solvents. 2. D2O-H2O solute isotope effects on the enthalpy of water dissolution in nitromethane, acetonitrile and propylene carbonate at 298.15 K
    Ivanov, Evgeniy V.
    Smirnov, Valeriy I.
    THERMOCHIMICA ACTA, 2010, 511 (1-2) : 198 - 201