HYDROSOL-PLANT: Structured Redox Reactors for H2 Production from Solar Thermochemical H2O Splitting

被引:10
作者
Lorentzou, Souzana [1 ]
Zygogianni, Alexandra [1 ]
Pagkoura, Chrysoula [1 ]
Karagiannakis, George [1 ]
Konstandopoulos, Athanasios G. [1 ,2 ]
Saeck, Jan Peter [3 ]
Breuer, Stefan [3 ]
Lange, Matthias [3 ]
Lapp, Justin [3 ]
Fend, Thomas [3 ]
Roeb, Martin [3 ]
Jose Gonzalez, Aurelio [1 ,4 ]
Vidal Delgado, Alfonso [4 ]
Brouwer, Jan Peter [5 ]
Makkus, Robert C. [5 ]
Kiartzis, Spyros J. [6 ]
机构
[1] Ctr Res & Technol Hellas, Chem Proc & Energy Resources Inst, Aerosol & Particle Technol Lab, 6th Km Charilaou Thermi Rd, Thessaloniki 57001, Greece
[2] Aristotle Univ Thessaloniki, Dept Chem Engn, Thessaloniki 54006, Greece
[3] DLR, Inst Solar Res, D-51147 Cologne, Germany
[4] CIEMAT, Av Complutense 40, Madrid 28040, Spain
[5] HYGEAR, Westervoortsedijk 73, NL-6827 AV Arnhem, Netherlands
[6] HELPE RES, 8A Chimarras Str, Maroussi 15125, Greece
来源
INTERNATIONAL CONFERENCE ON CONCENTRATING SOLAR POWER AND CHEMICAL ENERGY SYSTEMS (SOLARPACES 2017) | 2018年 / 2033卷
关键词
HYDROGEN-PRODUCTION; WATER; CYCLES; CERIA; CO2;
D O I
10.1063/1.5067144
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The "holy grail" of solar chemistry and solar engineering, is the technical storage of solar energy into a more easily transformable and transportable form, namely an energy carrier such as H-2. The two-step redox-based solar thermochemical H2O splitting cycle is considered to be among the most promising approaches for the production of H-2 from entirely renewable sources (solar energy and water). In this redox cycle an active material is initially reduced thermally under inert atmosphere and at the next step it is oxidized from H2O producing H-2. The materials that have been in the core of solar chemistry research are metal oxides such as ferrites, cerium oxides, perovskites, etc. The reactor types that are being investigated for the redox thermochemical splitting of H2O are either powder-particle reactors or structured reactors. In the current work Ni-ferrite and Ce-oxide structured into different monolithic bodies (honeycombs, foams) were evaluated w.r.t. their redox activity. Based on this investigation, the most promising structure was further scaled-up for the construction of the full-scale reactors of the HYDROSOL-PLANT solar plant installation.
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页数:11
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