Fabrication of durable and flexible single-walled carbon nanotube transparent conductive films

被引:21
作者
Devaraju, Subramani [1 ]
Lee, Taeheon [1 ]
Mohanty, Aruna Kumar [1 ]
Hong, Young Kun [1 ]
Yoon, Kwan Han [2 ]
Lee, Young Sil [3 ]
Han, Jong Hun [4 ]
Paik, Hyun-jong [1 ]
机构
[1] Pusan Natl Univ, Dept Polymer Sci & Engn, 2 Busandaehak Ro 63beon Gil, Busan 609735, South Korea
[2] Kumoh Natl Inst Technol, Dept Polymer Sci & Engn, 1 Yangho Dong, Gumi 730701, Gyeongbuk, South Korea
[3] Kumoh Natl Inst Technol, Ind Acad Cooperat Fdn, 1 Yangho Dong, Gumi 730701, Gyeongbuk, South Korea
[4] Chonnam Natl Univ, Sch Chem Engn, 77 Yongbong Ro, Gwangju 500757, South Korea
基金
新加坡国家研究基金会;
关键词
NONCOVALENT FUNCTIONALIZATION; ACID TREATMENT; DISPERSION; STABILITY; WATER; SOLUBILIZATION; GRAPHENE; DESIGN; NAFION;
D O I
10.1039/c7ra01180f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In the present work, flexible, durable, transparent, conductive films (TCFs) were fabricated with the use of aqueous dispersed single-walled carbon nanotubes (SWCNTs). A small amount of the synthesized sulfonated poly(ether sulfone) (SPES) was used to effectively disperse SWCNTs with high aspect ratios. The lengths and heights of the dispersed SWCNTs were 2.5 +/- 1.0 mu m and 2 +/- 1 nm, as determined by TEM and AFM, respectively. TCFs were fabricated using spray coating on a PET substrate; the best performance among the TCFs was achieved with a sheet resistance (R-s) of 125 Omega sq(-1) and optical transmittance of 87.1%. Moreover, no appreciable change in the R-s was observed after repeated bending cycles and adhesive peel-off tests, which indicate that SPES acts as a good dispersant and effective binder for the improvement in durability and adhesion behavior of the resulting TCFs in the absence of additional binders. Therefore, this material holds great potential for scalable and facile production of flexible SWCNT-TCFs for various electronic applications.
引用
收藏
页码:19267 / 19272
页数:6
相关论文
共 61 条
[1]   Carbon nanotubes in cancer therapy: a more precise look at the role of carbon nanotube-polymer interactions [J].
Adeli, Mohsen ;
Soleyman, Rouhollah ;
Beiranvand, Zahra ;
Madani, Fahimeh .
CHEMICAL SOCIETY REVIEWS, 2013, 42 (12) :5231-5256
[2]   Carbon nanotube field-effect-transistor-based biosensors [J].
Allen, Brett Lee ;
Kichambare, Padmakar D. ;
Star, Alexander .
ADVANCED MATERIALS, 2007, 19 (11) :1439-1451
[3]  
[Anonymous], 2009, J SENS
[4]   Controlling Adhesion Properties of SWCNT-PET Films Prepared by Wet Deposition [J].
Azoubel, Suzanna ;
Magdassi, Shlomo .
ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (12) :9265-9271
[5]   High Population of Individualized SWCNTs through the Adsorption of Water-Soluble Perylenes [J].
Backes, Claudia ;
Schmidt, Cordula D. ;
Hauke, Frank ;
Boettcher, Christoph ;
Hirsch, Andreas .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (06) :2172-2184
[6]   Covalent surface chemistry of single-walled carbon nanotubes [J].
Banerjee, S ;
Hemraj-Benny, T ;
Wong, SS .
ADVANCED MATERIALS, 2005, 17 (01) :17-29
[7]   Carbon nanotubes - the route toward applications [J].
Baughman, RH ;
Zakhidov, AA ;
de Heer, WA .
SCIENCE, 2002, 297 (5582) :787-792
[8]   Dispersion of multi-walled carbon nanotubes in an aqueous medium by water-dispersible conjugated polymer nanoparticles [J].
Baykal, Beril ;
Ibrahimova, Vuesala ;
Er, Gizem ;
Bengue, Erman ;
Tuncel, Doenues .
CHEMICAL COMMUNICATIONS, 2010, 46 (36) :6762-6764
[9]   Graphene Versus Carbon Nanotubes in Electronic Devices [J].
Biswas, Chandan ;
Lee, Young Hee .
ADVANCED FUNCTIONAL MATERIALS, 2011, 21 (20) :3806-3826
[10]  
Chen K., 2013, Adv. Chem. Eng. Sci, V3, P105, DOI 10.4236/aces.2013.31013