Progress in MgCl2 supported Ziegler-Natta catalyzed polyolefin products and applications

被引：35

作者：

Trivedi, Parthiv M. ^{[1
]}

Gupta, Virendra Kumar ^{[1
]}

机构：

[1] Reliance Ind Ltd, Reliance Res & Dev Ctr, Polymer Synth & Catalysis Grp, RCP, Navi Mumbai 400701, Maharashtra, India

来源：

JOURNAL OF POLYMER RESEARCH | 2021年 / 28卷 / 02期

关键词：

Ziegler-natta catalyst; Internal and external electron donors; Alkyl aluminium co-catalysts; Polyolefin product and applications; MOLECULAR-WEIGHT POLYETHYLENE; HIGH-DENSITY POLYETHYLENE; OLEFIN POLYMERIZATION CATALYSIS; ORIENTED POLYPROPYLENE FIBERS; EXTERNAL ALKOXYSILANE DONORS; MELT STRENGTH POLYPROPYLENE; HOT-COMPACTION BEHAVIOR; ULTRA-DRAWING BEHAVIOR; GROWN CARBON-FIBERS; PROPYLENE POLYMERIZATION;

D O I：

10.1007/s10965-021-02412-5

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The innovation of Ziegler-Natta (Z-N) catalysts opened a novel aspect of chemistry in terms of polyolefin formation. Significant progress of more than fifty years in catalytic olefin polymerization simplified polyolefin production by optimizing the reaction conditions and internal donors. In this review, we particularly emphasized on recent development on different internal donor based Z-N catalyst systems, the role of external electron donors and co-catalyst chemistry. Furthermore, the Ziegler-Natta catalyst system, polymerization reaction, and polymer process technologies gradually upgrading to produce different polyolefin products. In particular, polyolefin fibers, composites, foam, blends and polyolefin-based 3D-printing products targeted in this review for substantial benefits of both society and highly diversified industries.

引用

页数：20

共 265 条

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