Dielectric behaviour of UV-crosslinked sulfonated poly (ether ether ketone) with methyl cellulose (SPEEK-MC) as proton exchange membrane

被引:27
作者
Ramly, N. N. [1 ,4 ]
Aini, N. A. [1 ,4 ]
Sahli, N. [1 ,4 ]
Aminuddin, S. F. [3 ]
Yahya, M. Z. A. [2 ]
Ali, A. M. M. [1 ,4 ]
机构
[1] Univ Teknol MARA, Fac Appl Sci, Shah Alam, Selangor, Malaysia
[2] Univ Pertahanan Nas Malaysia, Fac Sci & Def Technol, Kuala Lumpur, Malaysia
[3] Univ Teknol MARA, Ctr Fdn Studies, Puncak Alam 42300, Selangor, Malaysia
[4] Univ Teknol MARA, Inst Sci, Shah Alam, Selangor, Malaysia
关键词
Proton exchange membrane fuel cells; UV crosslink; Sulfonated poly ether ether ketone; Methyl cellulose; Benzoin ethyl ether; Dielectric; LINKING; CONDUCTIVITY; BLENDS;
D O I
10.1016/j.ijhydene.2016.05.015
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Proton exchange membrane materials based on sulfonated poly ether ether ketone (SPEEK) with Methyl Cellulose (MC) are developed by solution cast technique and exposed to UV radiation with Bezoin Ethyl Ether (BEE) as photoinitiator. The addition of MC into SPEEK polymer enhances the conductivity up to 8.7 x 10(-3) Scm(-1) at 30 degrees C temperature and 80% relative humidity. This new crosslinked hybrid membrane shows good prospect for the use as proton exchange membrane in fuel cell. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:9284 / 9292
页数:9
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