Dielectric behaviour of UV-crosslinked sulfonated poly (ether ether ketone) with methyl cellulose (SPEEK-MC) as proton exchange membrane

被引:27
作者
Ramly, N. N. [1 ,4 ]
Aini, N. A. [1 ,4 ]
Sahli, N. [1 ,4 ]
Aminuddin, S. F. [3 ]
Yahya, M. Z. A. [2 ]
Ali, A. M. M. [1 ,4 ]
机构
[1] Univ Teknol MARA, Fac Appl Sci, Shah Alam, Selangor, Malaysia
[2] Univ Pertahanan Nas Malaysia, Fac Sci & Def Technol, Kuala Lumpur, Malaysia
[3] Univ Teknol MARA, Ctr Fdn Studies, Puncak Alam 42300, Selangor, Malaysia
[4] Univ Teknol MARA, Inst Sci, Shah Alam, Selangor, Malaysia
关键词
Proton exchange membrane fuel cells; UV crosslink; Sulfonated poly ether ether ketone; Methyl cellulose; Benzoin ethyl ether; Dielectric; LINKING; CONDUCTIVITY; BLENDS;
D O I
10.1016/j.ijhydene.2016.05.015
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Proton exchange membrane materials based on sulfonated poly ether ether ketone (SPEEK) with Methyl Cellulose (MC) are developed by solution cast technique and exposed to UV radiation with Bezoin Ethyl Ether (BEE) as photoinitiator. The addition of MC into SPEEK polymer enhances the conductivity up to 8.7 x 10(-3) Scm(-1) at 30 degrees C temperature and 80% relative humidity. This new crosslinked hybrid membrane shows good prospect for the use as proton exchange membrane in fuel cell. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:9284 / 9292
页数:9
相关论文
共 29 条
  • [1] Aini NA, 2012, INT J ELECTROCHEM SC, V7, P8226
  • [2] Crystallinity and dielectric relaxations in semi-crystalline poly(ether ether ketone)
    Arous, M.
    Ben Arnor, I.
    Kallel, A.
    Fakhfakh, Z.
    Perrier, G.
    [J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2007, 68 (07) : 1405 - 1414
  • [3] Sulfonated polyether ether ketone (SPEEK)-based composite proton exchange membrane reinforced with nanofibers for microbial electrolysis cells
    Chae, Kyu-Jung
    Kim, Kyoung-Yeol
    Choi, Mi-Jin
    Yang, Euntae
    Kim, In S.
    Ren, Xianghao
    Lee, Mooseok
    [J]. CHEMICAL ENGINEERING JOURNAL, 2014, 254 : 393 - 398
  • [4] Crosslinked sulfonated poly(arylene ether sulfone)/silica hybrid membranes for high temperature proton exchange membrane fuel cells
    Chun, Jeong Hwan
    Kim, Sang Gon
    Lee, Ji Young
    Hyeon, Dong Hun
    Chun, Byung-Hee
    Kim, Sung Hyun
    Park, Ki Tae
    [J]. RENEWABLE ENERGY, 2013, 51 : 22 - 28
  • [5] Analysis of electrochemical impedance spectroscopy in proton exchange membrane fuel cells
    Gomadam, PM
    Weidner, JW
    [J]. INTERNATIONAL JOURNAL OF ENERGY RESEARCH, 2005, 29 (12) : 1133 - 1151
  • [6] Cross-linked sulfonated poly (ether ether ketone) (SPEEK)/reactive organoclay nanocomposite proton exchange membranes (PEM)
    Hande, Varsha R.
    Rath, Sangram K.
    Rao, Swati
    Patri, M.
    [J]. JOURNAL OF MEMBRANE SCIENCE, 2011, 372 (1-2) : 40 - 48
  • [7] Photo-irradiation for preparation, modification and stimulation of polymeric membranes
    He, Dongming
    Susanto, Heru
    Ulbricht, Mathias
    [J]. PROGRESS IN POLYMER SCIENCE, 2009, 34 (01) : 62 - 98
  • [8] Building bridges: Crosslinking of sulfonated aromatic polymers-A review
    Hou, Hongying
    Di Vona, Maria Luisa
    Knauth, Philippe
    [J]. JOURNAL OF MEMBRANE SCIENCE, 2012, 423 : 113 - 127
  • [9] Kader MFHAE, 2012, IONICS KIEL, V19, P361
  • [10] Thermogravimetric analysis of SPEEK membranes: Thermal stability, degree of sulfonation and cross-linking reaction
    Knauth, P.
    Hou, H.
    Bloch, E.
    Sgreccia, E.
    Di Vona, M. L.
    [J]. JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2011, 92 (02) : 361 - 365