Organic syntheses catalyzed by superacidic metal oxides: sulfated zirconia and related compounds

被引：110
作者：
Arata, Kazushi [1 ]
机构：
[1] Hokkaido Univ, Dept Sci, Hakodate, Hokkaido 0408567, Japan
来源：
GREEN CHEMISTRY | 2009年 / 11卷 / 11期
关键词：
SOLID-ACID CATALYSTS; FRIEDEL-CRAFTS-ACYLATION; HETEROGENEOUS RECYCLABLE CATALYST; SOLVENT-FREE CONDITIONS; LIQUID-PHASE; EFFICIENT SYNTHESIS; STEREOCONTROLLED GLYCOSIDATIONS; ENVIRONMENTALLY BENIGN; BENZOIC ANHYDRIDE; ACETIC-ACID;
D O I：
10.1039/b822795k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Recent studies on organic syntheses catalyzed by solid superacids, which are sulfate-supported metal oxides and tungsten- or molybdenum-supported metal oxides, are reviewed. The synthetic reactions are Friedel-Crafts acylations, reactions between amines and ketones, esterifications of acids with alcohols, and others. The catalysts are satisfactorily active in a heterogeneous liquid-solid system, recoverable, and reusable, and they offer new opportunities for developing environmentally benign and friendly processes in organic syntheses.
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收藏
页码：1719 / 1728
页数：10
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