Kinetics of supramolecular crystallization of concentrated suspensions of monodisperse spherical silica particles

被引：12
|
作者：
Serdobintseva, VV [1 ]
Danilyuk, AF
Vosel, SV
Kalinin, DV
机构：
[1] Inst Mineral & Petrog, Novosibirsk 630090, Russia
[2] Boreskov Inst Catalysis, Novosibirsk 630090, Russia
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 1999年 / 68卷 / 02期
关键词：
silica; monodisperse particles; supramolecular crystallization; kinetics;
D O I：
10.1007/BF02475528
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The kinetics of supramolecular crystallization of concentrated suspensions is three-dimensional and follows the Avrami-Erofeev equation: A = 1 - exp[-(kt)(m)], where m = 4. The rate constant k is proportional to the probability of the appearance of a crystallization center in unit volume in unit time and the linear crystal growth rate, which is determined experimentally.
引用
收藏
页码：387 / 391
页数：5
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