Single Molecular Wires Connecting Metallic and Insulating Surface Areas

被引：76

作者：

Bombis, Christian ^{[1
,2
]}

Ample, Francisco ^{[3
]}

Lafferentz, Leif ^{[1
,2
]}

Yu, Hao ^{[4
]}

Hecht, Stefan ^{[4
]}

Joachim, Christian ^{[3
]}

Grill, Leonhard ^{[1
,2
]}

机构：

[1] Free Univ Berlin, Expt Phys Dept, D-14195 Berlin, Germany

[2] Max Planck Soc, Fritz Haber Inst, D-14195 Berlin, Germany

[3] CNRS, CEMES, Nanosci Grp, F-31055 Toulouse, France

[4] Humboldt Univ, Dept Chem, D-12489 Berlin, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 52期

关键词：

molecular electronics; polymers; scanning probe microscopy; thin films; transition metals; SCANNING TUNNELING MICROSCOPE; THIN-FILMS; FORCE MICROSCOPY; SPECTROSCOPY; NACL; MANIPULATION; ADSORBATES; AU(111);

D O I：

10.1002/anie.200904645

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(figure represented) Totally wired: A particular molecular adsorption geometry can be prepared by adsorbing single conjugated polyfluorene chains partially on a clean Au(111) surface and partially on a thin crystalline NaCl film, thus connecting metallic and insulating surface areas. This configuration allows the electronic characterization of one and the same molecular wire as a function of its atomic-scale environment in a planar configuration. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：9966 / 9970

页数：5

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