Hydrodeoxygenation upgrading of pine sawdust bio-oil using zinc metal with zero valency

被引：36
作者：
Cheng, Shouyun [1 ]
Wei, Lin [1 ]
Julson, James [1 ]
Muthukumarappan, Kasiviswanathan [1 ]
Kharel, Parashu Ram [2 ]
Cao, Yuhe [1 ]
Boakye, Eric [3 ]
Raynie, Douglas [3 ]
Gu, Zhengrong [1 ]
机构：
[1] South Dakota State Univ, Agr & Biosyst Engn Dept, 1400 North Campus Dr, Brookings, SD 57007 USA
[2] South Dakota State Univ, Dept Phys, Brookings, SD 57007 USA
[3] South Dakota State Univ, Dept Chem & Biochem, Brookings, SD 57007 USA
来源：
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS | 2017年 / 74卷
关键词：
Bio-oil; In situ hydrodeoxygenation; Zinc; Hydrolysis; Hydrogen; Hydrocarbons; AQUEOUS-PHASE HYDRODEOXYGENATION; FAST PYROLYSIS OIL; HYDROGEN-PRODUCTION; HYDROCARBON BIOFUEL; CATALYTIC CRACKING; THERMOGRAVIMETRIC ANALYSIS; PHENOLIC-COMPOUNDS; CARBOXYLIC-ACIDS; CAMELINA OIL; ZNO NANORODS;
D O I：
10.1016/j.jtice.2017.02.011
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Hydrodeoxygenation (HDO) is an effective method for bio-oil upgrading. However, the high hydrogen consumption resulted in high bio-oil upgrading cost. In this study, an novel method of hydrogen generation from water for bio-oil HDO was reported. Zinc metal with zero valency was used to generate hydrogen through zinc hydrolysis reaction in the bio-oil HDO process. The effects of different temperatures (20 degrees C, 250 degrees C, 300 degrees C, 350 degrees C, 400 degrees C) on in situ bio-oil HDO was investigated. The results showed that high temperatures resulted in high hydrogen yield that led to promoted HDO activity over zinc metal-based materials. Although 20 degrees C bio-oil HDO process generated the highest oil phase yield at 14.07%, 400 degrees C bio-oil upgrading process produced upgraded bio-oil with highest hydrocarbons content at 68.95%. Physicochemical properties of raw bio-oil improved significantly after bio-oil HDO upgrading at higher temperatures (250 degrees C, 300 degrees C 350 degrees C and 400 degrees C). The pH of upgraded bio-oils (5.70-6.49) increased significantly compared to raw bio-oil (3.24). The higher heating value of upgraded bio-oils (28.67-33.43 MJ/kg) increased significantly compared to raw bio-oil (15.54 MJ/kg), and valuable hydrocarbons content improved significantly from 16.94% in raw bio-oil to 37.86%-68.95% in upgraded bio-oils. (C) 2017 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
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页码：146 / 153
页数：8
相关论文
共 57 条
  • [41] Wei L, 2016, T ASABE, V59, P717
  • [42] Blue luminescent centers and microstructural evaluation by XPS and Raman in ZnO thin films annealed in vacuum, N2 and O2
    Wei, X. Q.
    Man, B. Y.
    Liu, M.
    Xue, C. S.
    Zhuang, H. Z.
    Yang, C.
    [J]. PHYSICA B-CONDENSED MATTER, 2007, 388 (1-2) : 145 - 152
  • [43] Thermogravimetric analysis of the ZnO/Zn water splitting cycle
    Weidenkaff, A
    Reller, AW
    Wokaun, A
    Steinfeld, A
    [J]. THERMOCHIMICA ACTA, 2000, 359 (01) : 69 - 75
  • [44] Heterostructures of ZnO-Zn coaxial nanocables and ZnO nanotubes
    Wu, JJ
    Liu, SC
    Wu, CT
    Chen, KH
    Chen, LC
    [J]. APPLIED PHYSICS LETTERS, 2002, 81 (07) : 1312 - 1314
  • [45] Synthesis of ZnO nanorod and the annealing effect on its photoluuminescence property
    Wu, LL
    Wu, YS
    Pan, XR
    Kong, FY
    [J]. OPTICAL MATERIALS, 2006, 28 (04) : 418 - 422
  • [46] Preparation of ZnO nanorods and optical characterizations
    Wu, LL
    Wu, YS
    Lü, W
    [J]. PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES, 2005, 28 (01) : 76 - 82
  • [47] Xu JF, 1999, J SOLID STATE CHEM, V147, P516, DOI 10.1006/1999.8409
  • [48] Two-step catalytic hydrodeoxygenation of fast pyrolysis oil to hydrocarbon liquid fuels
    Xu, Xingmin
    Zhang, Changsen
    Liu, Yonggang
    Zhai, Yunpu
    Zhang, Ruiqin
    [J]. CHEMOSPHERE, 2013, 93 (04) : 652 - 660
  • [49] The Catalytic Valorization of Lignin for the Production of Renewable Chemicals
    Zakzeski, Joseph
    Bruijnincx, Pieter C. A.
    Jongerius, Anna L.
    Weckhuysen, Bert M.
    [J]. CHEMICAL REVIEWS, 2010, 110 (06) : 3552 - 3599
  • [50] Review of biomass pyrolysis oil properties and upgrading research
    Zhang Qi
    Chang Jie
    Wang Tiejun
    Xu Ying
    [J]. ENERGY CONVERSION AND MANAGEMENT, 2007, 48 (01) : 87 - 92
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