Selective Conversion of Alcohols into Alkyl Iodides Using a Thioiminium Salt

被引：17

作者：

Ellwood, Adam R. ^{[1
]}

Porter, Michael J. ^{[1
]}

机构：

[1] UCL, Dept Chem, Christopher Ingold Labs, London WC1H 0AJ, England

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2009年 / 74卷 / 20期

关键词：

CHLOROTRIMETHYLSILANE SODIUM IODIDE; HYDROXYL-GROUPS; REAGENT SYSTEM; EFFICIENT; HALIDES; REPLACEMENT; HALOGENATION; CONVENIENT; INVERSION; SULFIDES;

D O I：

10.1021/jo901415n

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of a range of primary and secondary alcohols with MeSCH=NMe2+ I- affords the corresponding alkyl iodides in excellent yield with straightforward purification. Selective formation of a primary iodide in the presence of a secondary alcohol can be achieved.

引用

页码：7982 / 7985

页数：4

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