Synthesis, properties and crystal structures of pentamethylcyclopentadienyl- and cyclopentadienyl-ruthenium(II) diphenylphosphine complexes

被引：9

作者：

Lubian, RT ^{[1
]}

PazSandoval, MA ^{[1
]}

机构：

[1] INST POLITECN NACL,CTR INVEST & ESTUDIOS AVANZADOS,DEPT QUIM,MEXICO CITY 07000,DF,MEXICO

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 532卷 / 1-2期

关键词：

ruthenium; cyclopentadienyls; phosphines;

D O I：

10.1016/S0022-328X(96)06769-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis, characterization and single-crystal structure determination of chiral compounds (eta(5)-C5R5)Ru(pHph(2))(pph(3))Cl (R = H 3, R = Me 4) and prochiral Cp * Ru(PHPh2)(2)Cl (6) are described. Compound 6 has been available from reaction of PHPh2 and several starting materials. The X-ray structure comparison between 3, 4 and 6 allowed us to compare the influence of the phosphine, Cp and Cp * ligands in these half-sandwich compounds. In addition, a structural investigation was carried out on Cp*R(NBD)Cl(7).

引用

页码：17 / 29

页数：13

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