Rage Against Conformity: Ruthenium(II) Bisterpyridine Complexes Respond to Crystal Engineering Instructions with Whelming Results

被引：3
作者：
Iranmanesh, Hasti [1 ]
Arachchige, Kasun S. A. [1 ,2 ]
Donald, William A. [1 ]
Kyriacou, Niamh [1 ]
Shen, Chao [1 ]
Price, Jason R. [3 ]
Beves, Jonathon E. [1 ,4 ]
机构：
[1] Univ New South Wales, Sch Chem, Sydney, NSW 2052, Australia
[2] Univ Queensland, Sch Chem & Mol Biosci, Brisbane, Qld 4072, Australia
[3] Australian Synchrotron, 800 Blackburn Rd, Clayton, Vic 3168, Australia
[4] Nanjing Univ, Key State Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
来源：
AUSTRALIAN JOURNAL OF CHEMISTRY | 2017年 / 70卷 / 05期
基金：
美国国家科学基金会; 澳大利亚研究理事会;
关键词：
METAL-ORGANIC FRAMEWORKS; INTERMOLECULAR INTERACTIONS; 4,4'-BIPYRIDINE LIGAND; ENERGY-TRANSFER; SOLID-STATE; METALLOLIGAND; IRON(II); CAGES; BEHAVIOR; RU;
D O I：
10.1071/CH16620
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Four heteroleptic ruthenium(II) complexes of 4'-functionalised 2,2':6',2 ''-terpyridine are reported, along with their solid-state single-crystal X-ray structures. The complexes feature complementary hydrogen-bond donor (phenol) and acceptor (pyridyl) groups designed to assemble into one-dimensional polymers. In one example, the system obeys the programmed instructions to form a one-dimensional, self-complementary hydrogen-bonded polymer. In one other example, a water-bridged hydrogen-bonded polymer is formed. In the remaining two structures, aryl-aryl interactions dominate the intermolecular interactions, and outweigh the contribution of intermolecular hydrogen bonding.
引用
收藏
页码：529 / 537
页数：9
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