Effect of oxygen pressure on structure and properties of Bi1.5Zn1.0Nb1.5O7 pyrochlore thin films prepared by pulsed laser deposition

被引:27
作者
Zhang, Xiaohua [1 ]
Ren, Wei [1 ]
Shi, Peng [1 ]
Chen, Xiaofeng [1 ]
Wu, Xiaoqing [1 ]
机构
[1] Xi An Jiao Tong Univ, Key Lab, Minist Educ, Elect Mat Res Lab, Xian 710049, Peoples R China
基金
中国国家自然科学基金;
关键词
BZN thin films; Pulsed laser deposition; Oxygen pressure; Dielectric properties; Tunability; DIELECTRIC-PROPERTIES; DEPENDENCE; ORIENTATION; THICKNESS;
D O I
10.1016/j.apsusc.2009.10.020
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The Bi2O3-ZnO-Nb2O5 (BZN) cubic pyrochlore thin films were prepared on Pt/TiO2/SiO2/Si(1 0 0) substrates by using pulsed laser deposition process. The oxygen pressure was varied in the range of 5-50 Pa to investigate its effect on the structure and dielectric properties of BZN thin films. It is found that oxygen pressure during deposition plays an important role on structure and other properties of BZN films. The BZN films deposited at temperature of 650 degrees C and at O-2 pressure of 5 Pa have an amorphous BZN and Nb2O5 phases but exhibits a cubic pyrochlore structure with a preferential (2 2 2) orientation when the oxygen pressure increases to 10 Pa. Dielectric constant and loss tangent of the films deposited at 10 Pa are 185 and 0.0008 at 10 kHz, respectively. The dielectric tunability is about 10% at a dc bias field of 0.9 MV/cm. (C) 2009 Elsevier B. V. All rights reserved.
引用
收藏
页码:1861 / 1866
页数:6
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